ArticleNature communications2022
Following excited-state chemical shifts in molecular ultrafast x-ray photoelectron spectroscopy.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed.
- Time-resolved core-level photoelectron spectroscopy of glycine fragmentation: a case study on the capabilities and limitations of site-selective probes at XFELs.Faraday discussions · 2026Article
- Photoinduced Enhancement of Chemical Shift Sensitivity to Local Vibrations.Journal of the American Chemical Society · 2026Article
- Spatial Mapping of Valence Excited-State Landscapes Using Time-Resolved Shake-Down Spectroscopy.The journal of physical chemistry. A · 2026Article
- Ultrafast metal-to-ligand electron transfer driven by bond shortening revealed through dual-edge computational X-ray spectroscopy.Communications chemistry · 2026Article
- Transient X‑ray Absorption Signatures of Photodissociation Pathways and Conical Intersection Dynamics in Phenol.JACS Au · 2026Article
- Multireference Equation-of-Motion-Driven Similarity Renormalization Group for X-ray Photoelectron Spectra.Journal of chemical theory and computation · 2025Article
- Shake-Down Spectroscopy as State- and Site-Specific Probe of Ultrafast Chemical Dynamics.Journal of the American Chemical Society · 2025Article
- Unraveling the Relaxation Dynamics of Uracil: Insights from Time-Resolved X-ray Photoelectron Spectroscopy.Journal of the American Chemical Society · 2025Article
- Roadmap for Molecular Benchmarks in Nonadiabatic Dynamics.The journal of physical chemistry. A · 2025Review
- An Improved Virtual Orbital Driven Similarity Renormalization Group Approach for Core-Ionized and Core-Excited States.Journal of chemical theory and computation · 2025Article
- Efficient Photothermoelectric Conversion of CSS@BP/BiAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Direct Observation of theThe journal of physical chemistry letters · 2025Article
- Direct observation of ultrafast symmetry reduction during internal conversion of 2-thiouracil using Coulomb explosion imaging.Nature communications · 2025Article
- Different Photodissociation Mechanisms in Fe(CO)The journal of physical chemistry letters · 2024Article
- Benchmark Study of Core-Ionization Energies with the Generalized Active Space-Driven Similarity Renormalization Group.Journal of chemical theory and computation · 2024Article
- The Role of Momentum Partitioning in Covariance Ion Imaging Analysis.The journal of physical chemistry. A · 2024Article
- Chemical bond reorganization in intramolecular proton transfer revealed by ultrafast X-ray photoelectron spectroscopy.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Time-resolving state-specific molecular dissociation with XUV broadband absorption spectroscopy.Science advances · 2023Article
- Enhancing the Washing Durability and Electrical Longevity of Conductive Polyaniline-Grafted Polyester Fabrics.ACS omega · 2023Article
- Time-Resolved X-ray Photoelectron Spectroscopy: Ultrafast Dynamics in CSThe journal of physical chemistry letters · 2023Article
Corrections and comments
- Erratum issued
Authors and funding
20 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The conversion of photon energy into other energetic forms in molecules is accompanied by charge moving on ultrafast timescales. We directly observe the charge motion at a specific site in an electronically excited molecule using time-resolved x-ray photoelectron spectroscopy (TR-XPS). We extend the concept of static chemical shift from conventional XPS by the excited-state chemical shift (ESCS), which is connected to the charge in the framework of a potential model. This allows us to invert TR-XPS spectra to the dynamic charge at a specific atom. We demonstrate the power of TR-XPS by using sulphur 2p-core-electron-emission probing to study the UV-excited dynamics of 2-thiouracil. The method allows us to discover that a major part of the population relaxes to the molecular ground state within 220-250 fs. In addition, a 250-fs oscillation, visible in the kinetic energy of the TR-XPS, reveals a coherent exchange of population among electronic states.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.