ArticleNature communications2022
Cyclopentadienyl coordination induces unexpected ionic Am-N bonding in an americium bipyridyl complex.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed.
- Plutonium(III) versus uranium(III) and samarium(III) in small molecule activation chemistry.Nature communications · 2026Article
- Magnetic hysteresis in 1D organometallic lanthanide chain compounds containing 4,4'-bipyridine.Chemical science · 2025Article
- Transuranium organometallic chemistry.Nature reviews. Chemistry · 2025Review
- N-Heterocyclic Carbene to Actinide d-Based π-bonding Correlates with Observed Metal-Carbene Bond Length Shortening Versus Lanthanide Congeners.Journal of the American Chemical Society · 2024Article
- Altering the spectroscopy, electronic structure, and bonding of organometallic curium(III) upon coordination of 4,4'-bipyridine.Nature communications · 2023Article
- Carbene Complexes of Neptunium.Journal of the American Chemical Society · 2022Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Variations in bonding between trivalent lanthanides and actinides is critical for reprocessing spent nuclear fuel. The ability to tune bonding and the coordination environment in these trivalent systems is a key factor in identifying a solution for separating lanthanides and actinides. Coordination of 4,4'-bipyridine (4,4'-bpy) and trimethylsilylcyclopentadienide (Cp') to americium introduces unexpectedly ionic Am-N bonding character and unique spectroscopic properties. Here we report the structural characterization of (Cp'
Identifiers
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Registered trials
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