Evidence map›Paper›PMID 35012157›Full record

ArticlePolymers2021

Random and Diblock Thermoresponsive Oligo(ethylene glycol)-Based Copolymers Synthesized via Photo-Induced RAFT Polymerization.

Alexey Sivokhin, Dmitry Orekhov, Oleg Kazantsev, Olga Sivokhina, Sergey Orekhov, Denis Kamorin, Ksenia Otopkova, Michael Smirnov, Rostislav Karpov

Abstract read
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In one paragraph

Article in Polymers, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Alexey SivokhinLaboratory of Acrylic Monomers and Polymers, Department of Chemical and Food Technologies, Dzerzhinsk Polytechnic Institute, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 24 Minin Street, 603950 Nizhny Novgorod, Russia.ORCID 0000-0002-6387-6574
Dmitry OrekhovLaboratory of Acrylic Monomers and Polymers, Department of Chemical and Food Technologies, Dzerzhinsk Polytechnic Institute, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 24 Minin Street, 603950 Nizhny Novgorod, Russia.ORCID 0000-0002-2820-4705
Oleg KazantsevLaboratory of Acrylic Monomers and Polymers, Department of Chemical and Food Technologies, Dzerzhinsk Polytechnic Institute, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 24 Minin Street, 603950 Nizhny Novgorod, Russia.
Olga SivokhinaV.A. Kargin Research Institute of Chemistry and Technology of Polymers with Pilot Plant, 606000 Dzerzhinsk, Russia.
Sergey OrekhovLaboratory of Acrylic Monomers and Polymers, Department of Chemical and Food Technologies, Dzerzhinsk Polytechnic Institute, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 24 Minin Street, 603950 Nizhny Novgorod, Russia.
Denis KamorinLaboratory of Acrylic Monomers and Polymers, Department of Chemical and Food Technologies, Dzerzhinsk Polytechnic Institute, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 24 Minin Street, 603950 Nizhny Novgorod, Russia.
Ksenia OtopkovaLaboratory of Acrylic Monomers and Polymers, Department of Chemical and Food Technologies, Dzerzhinsk Polytechnic Institute, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 24 Minin Street, 603950 Nizhny Novgorod, Russia.
Michael SmirnovLaboratory of Acrylic Monomers and Polymers, Department of Chemical and Food Technologies, Dzerzhinsk Polytechnic Institute, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 24 Minin Street, 603950 Nizhny Novgorod, Russia.
Rostislav KarpovLaboratory of Acrylic Monomers and Polymers, Department of Chemical and Food Technologies, Dzerzhinsk Polytechnic Institute, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 24 Minin Street, 603950 Nizhny Novgorod, Russia.

Funding

Russian Science Foundation 21-73-20212
6 · The paper itself

Abstract

Amphiphilic random and diblock thermoresponsive oligo(ethylene glycol)-based (co)polymers were synthesized via photoiniferter polymerization under visible light using trithiocarbonate as a chain transfer agent. The effect of solvent, light intensity and wavelength on the rate of the process was investigated. It was shown that blue and green LED light could initiate RAFT polymerization of macromonomers without an exogenous initiator at room temperature, giving bottlebrush polymers with low dispersity at sufficiently high conversions achieved in 1-2 h. The pseudo-living mechanism of polymerization and high chain-end fidelity were confirmed by successful chain extension. Thermoresponsive properties of the copolymers in aqueous solutions were studied via turbidimetry and laser light scattering. Random copolymers of methoxy- and alkoxy oligo(ethylene glycol) methacrylates of a specified length formed unimolecular micelles in water with a hydrophobic core consisting of a polymer backbone and alkyl groups and a hydrophilic oligo(ethylene glycol) shell. In contrast, the diblock copolymer formed huge multimolecular micelles.

Indexed as

block copolymeroligo(ethylene glycol) methacrylatesphotoiniferter polymerizationself-assemblyself-foldingthermoresponsive polymer

Identifiers

PMID35012157
PMCPMC8747269

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.