ArticleMolecules (Basel, Switzerland)2021
SOMOphilic Alkynylation of Unreactive Alkenes Enabled by Iron-Catalyzed Hydrogen Atom Transfer.
Article in Molecules (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
3 citing papers in PubMed.
- Iron-catalyzed radical Markovnikov hydrohalogenation and hydroazidation of alkenes.Nature communications · 2024Article
- Isocyanides as Acceptor Groups in MHAT Reactions with Unactivated Alkenes.Organic letters · 2023Article
- Polyisobutylenes with Controlled Molecular Weight and Chain-End Structure: Synthesis and Actual Applications.Polymers · 2023Review
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
We report an efficient and practical iron-catalyzed hydrogen atom transfer protocol for assembling acetylenic motifs into functional alkenes. Diversities of internal alkynes could be obtained from readily available alkenes and acetylenic sulfones with excellent Markovnikov selectivity. An iron hydride hydrogen atom transfer catalytic cycle was described to clarify the mechanism of this reaction.
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Registered trials
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