Evidence map›Paper›PMID 35009995›Full record

ArticleNanomaterials (Basel, Switzerland)2021

A Blueprint for the Synthesis and Characterization of Thiolated Graphene.

Maxim K Rabchinskii, Victor V Sysoev, Sergei A Ryzhkov, Ilya A Eliseyev, Dina Yu Stolyarova, Grigorii A Antonov, Nikolai S Struchkov, Maria Brzhezinskaya, Demid A Kirilenko, Sergei I Pavlov and 7 more

Abstract read
In one paragraph

Article in Nanomaterials (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Article
  3. Facile Synthesis of Polypyrrole/MnONanomaterials (Basel, Switzerland) · 2025
    Article
  4. Article
  5. Article
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

17 authors.

Maxim K RabchinskiiIoffe Institute, Politekhnicheskaya St. 26, 194021 Saint Petersburg, Russia.ORCID 0000-0003-4264-7147
Victor V SysoevDepartment of Physics, Yuri Gagarin State Technical University of Saratov, 77 Polytechnicheskaya St., 410054 Saratov, Russia.ORCID 0000-0002-0372-1802
Sergei A RyzhkovIoffe Institute, Politekhnicheskaya St. 26, 194021 Saint Petersburg, Russia.
Ilya A EliseyevIoffe Institute, Politekhnicheskaya St. 26, 194021 Saint Petersburg, Russia.ORCID 0000-0001-9980-6191
Dina Yu StolyarovaNational Research Centre "Kurchatov Institute", Akademika Kurchatova pl. 1, 123182 Moscow, Russia.
Grigorii A AntonovIoffe Institute, Politekhnicheskaya St. 26, 194021 Saint Petersburg, Russia.
Nikolai S StruchkovCenter for Probe Microscopy and Nanotechnology, National Research University of Electronic Technology, Bld. 1, Shokin Square, 124498 Moscow, Russia.ORCID 0000-0002-7382-8058
Maria BrzhezinskayaHelmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, 14109 Berlin, Germany.
Demid A KirilenkoIoffe Institute, Politekhnicheskaya St. 26, 194021 Saint Petersburg, Russia.ORCID 0000-0002-1571-209X
Sergei I PavlovIoffe Institute, Politekhnicheskaya St. 26, 194021 Saint Petersburg, Russia.ORCID 0000-0001-9589-8017
Mihail E PalenovInstitute of Electronics and Telecommunications, Peter the Great St. Petersburg Polytechnic University (SPbPU), Polytechnicheskaya 29, 195251 Saint Petersburg, Russia.
Maxim V MishinInstitute of Electronics and Telecommunications, Peter the Great St. Petersburg Polytechnic University (SPbPU), Polytechnicheskaya 29, 195251 Saint Petersburg, Russia.
Olga E KvashenkinaInstitute of Electronics and Telecommunications, Peter the Great St. Petersburg Polytechnic University (SPbPU), Polytechnicheskaya 29, 195251 Saint Petersburg, Russia.
Pavel G GabdullinInstitute of Electronics and Telecommunications, Peter the Great St. Petersburg Polytechnic University (SPbPU), Polytechnicheskaya 29, 195251 Saint Petersburg, Russia.ORCID 0000-0002-2519-2577
Alexey S VarezhnikovDepartment of Physics, Yuri Gagarin State Technical University of Saratov, 77 Polytechnicheskaya St., 410054 Saratov, Russia.ORCID 0000-0002-0896-9102
Maksim A SolomatinDepartment of Physics, Yuri Gagarin State Technical University of Saratov, 77 Polytechnicheskaya St., 410054 Saratov, Russia.
Pavel N BrunkovIoffe Institute, Politekhnicheskaya St. 26, 194021 Saint Petersburg, Russia.ORCID 0000-0002-3400-4654

Funding

Ministry of Science and Higher Education of the Russian Federation contract No. 075-15-2020-934 dated 17.11.2020
6 · The paper itself

Abstract

Graphene derivatization to either engineer its physical and chemical properties or overcome the problem of the facile synthesis of nanographenes is a subject of significant attention in the nanomaterials research community. In this paper, we propose a facile and scalable method for the synthesis of thiolated graphene via a two-step liquid-phase treatment of graphene oxide (GO). Employing the core-level methods, the introduction of up to 5.1 at.% of thiols is indicated with the simultaneous rise of the C/O ratio to 16.8. The crumpling of the graphene layer upon thiolation without its perforation is pointed out by microscopic and Raman studies. The conductance of thiolated graphene is revealed to be driven by the Mott hopping mechanism with the sheet resistance values of 2.15 kΩ/sq and dependable on the environment. The preliminary results on the chemiresistive effect of these films upon exposure to ethanol vapors in the mix with dry and humid air are shown. Finally, the work function value and valence band structure of thiolated graphene are analyzed. Taken together, the developed method and findings of the morphology and physics of the thiolated graphene guide the further application of this derivative in energy storage, sensing devices, and smart materials.

Indexed as

2D materialsfunctionalizationgas sensorgraphenegraphene derivativesMott conductivitythiolsvalence band

Identifiers

PMID35009995
PMCPMC8746421

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.