Evidence map›Paper›PMID 35006643›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022

Evidence for Charge Delocalization in Diazafluorene Ligands Supporting Low-Valent [Cp*Rh] Complexes.

Wade C Henke, Jonah P Stiel, Victor W Day, James D Blakemore

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Mechanistic roles of metal- and ligand-protonated species in hydrogen evolution with [Cp*Rh] complexes.Proceedings of the National Academy of Sciences of the United States of America · 2023
    Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Wade C HenkeDepartment of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, KS 66045, USA.ORCID http://orcid.org/0000-0002-4574-8544
Jonah P StielDepartment of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, KS 66045, USA.
Victor W DayDepartment of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, KS 66045, USA.
James D BlakemoreDepartment of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, KS 66045, USA.ORCID http://orcid.org/0000-0003-4172-7460

Funding

TRAINING GRANT IN DYNAMIC ASPECTS OF CHEMICAL BIOLOGYT32GM008545 · NIGMS · UNIVERSITY OF KANSAS LAWRENCE · PI LAMB, AUDREY L · 1994 to 2019
$4.9M
Avance II 500 High Performance Digital NMR Spectrometer SystemS10RR024664 · NCRR · UNIVERSITY OF KANSAS LAWRENCE · PI VANDERVELDE, DAVID G · 2007 to 2007
$468k
AVIII HD 400 NMR spectrometer to replace existing DRX 400S10OD016360 · OD · UNIVERSITY OF KANSAS LAWRENCE · PI DOUGLAS, JUSTIN TRIGALET · 2014 to 2014
$297k
Arnold and Mabel Beckman Foundation Beckman Scholars Program at KUKansas Academy of Science Graduate Student Research GrantNational Science Foundation CHE-0946883National Science Foundation CHE-1625923National Science Foundation OIA-1833087NCRR NIH HHS S10 RR024664NIGMS NIH HHS T32 GM008545NIH HHS S10 OD016360NIH HHS S10OD016360NIH HHS S10RR024664NIH HHS T32 GM008545-25
6 · The paper itself

Abstract

Ligands based upon the 4,5-diazafluorene core are an important class of emerging ligands in organometallic chemistry, but the structure and electronic properties of these ligands have received less attention than they deserve. Here, we show that 9,9'-dimethyl-4,5-diazafluorene (Me

Indexed as

crystallographyelectrochemistryligandsredox chemistryrhodium

Identifiers

PMID35006643
PMCPMC8857064

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.