ArticleChemical science2021
Revealing redox isomerism in trichromium imides by anomalous diffraction.
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Unsymmetric bimetallic centres in metalloproteins and synthetic models.Nature reviews. Chemistry · 2026Review
- SISYPHOS: An automatic procedure for the serial refinement of single-crystal diffraction data in Olex2.Structural dynamics (Melville, N.Y.) · 2025Article
- Occupancy Determination from Resonant X-ray Diffraction.Inorganic chemistry · 2025Article
- Electronic Desymmetrization of CuInorganic chemistry · 2024Article
- Improvement of Single-Crystal Structures of Very Heavy Element Compounds by Refining Anomalous Dispersion Parameters.Inorganic chemistry · 2024Article
- Uncovering a CFAngewandte Chemie (International ed. in English) · 2023Article
- Metal Site-Specific Electrostatic Field Effects on a Tricopper(I) Cluster Probed by Resonant Diffraction Anomalous Fine Structure (DAFS).Inorganic chemistry · 2023Article
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Authors and funding
9 authors.
Funding
Abstract
In polynuclear biological active sites, multiple electrons are needed for turnover, and the distribution of these electrons among the metal sites is affected by the structure of the active site. However, the study of the interplay between structure and redox distribution is difficult not only in biological systems but also in synthetic polynuclear clusters since most redox changes produce only one thermodynamically stable product. Here, the unusual chemistry of a sterically hindered trichromium complex allowed us to probe the relationship between structural and redox isomerism. Two structurally isomeric trichromium imides were isolated: asymmetric terminal imide (
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