Evidence map›Paper›PMID 35003585›Full record

ArticleChemical science2021

Metal-catalyzed B-H acylmethylation of pyridylcarboranes: access to carborane-fused indoliziniums and quinoliziniums.

Hou-Ji Cao, Xing Wei, Fangxiang Sun, Xiaolei Zhang, Changsheng Lu, Hong Yan

Abstract read
In one paragraph

Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Hou-Ji CaoState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University Nanjing Jiangsu 210023 P. R. China hyan1965@nju.edu.cn zhangxiaolei1213@yahoo.com luchsh@nju.edu.cn.
Xing WeiState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University Nanjing Jiangsu 210023 P. R. China hyan1965@nju.edu.cn zhangxiaolei1213@yahoo.com luchsh@nju.edu.cn.
Fangxiang SunState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University Nanjing Jiangsu 210023 P. R. China hyan1965@nju.edu.cn zhangxiaolei1213@yahoo.com luchsh@nju.edu.cn.
Xiaolei ZhangState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University Nanjing Jiangsu 210023 P. R. China hyan1965@nju.edu.cn zhangxiaolei1213@yahoo.com luchsh@nju.edu.cn.
Changsheng LuState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University Nanjing Jiangsu 210023 P. R. China hyan1965@nju.edu.cn zhangxiaolei1213@yahoo.com luchsh@nju.edu.cn.ORCID https://orcid.org/0000-0002-6063-7754
Hong YanState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University Nanjing Jiangsu 210023 P. R. China hyan1965@nju.edu.cn zhangxiaolei1213@yahoo.com luchsh@nju.edu.cn.ORCID https://orcid.org/0000-0003-3993-0013

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Metal-catalyzed mono-acylmethylation of pyridylcarboranes has been realized using α-carbonyl sulfoxonium ylides as a coupling partner. The reaction features high efficiency, excellent site-selectivity and good functional group tolerance. In the presence of pyridyl and enolizable acylmethyl groups, a post-coordination mode has been proposed and validated by

Identifiers

PMID35003585
PMCPMC8654026

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.