Evidence map›Paper›PMID 34982848›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Lessons from an Array: Using an Electrode Surface to Control the Selectivity of a Solution-Phase Chemical Reaction.

Enqi Feng, Qiwei Jing, Kevin D Moeller

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Enqi FengDepartment of Chemistry, Washington University, St. Louis, MO 63130, USA.
Qiwei JingDepartment of Chemistry, Washington University, St. Louis, MO 63130, USA.
Kevin D MoellerDepartment of Chemistry, Washington University, St. Louis, MO 63130, USA.ORCID http://orcid.org/0000-0002-3893-5923

Funding

NEW METHODS FOR THE SYNTHESIS AND ANALYSIS OF ADDRESSABLE MOLECULAR LIBRARIESR01GM122747 · NIGMS · WASHINGTON UNIVERSITY · PI MOELLER, KEVIN DAVID · 2018 to 2021
$1.1M
National Science Foundation CHE-1764449National Science Foundation CHE-2002158NIGMS NIH HHS R01 GM122747NIH HHS 1R01 GM122747
6 · The paper itself

Abstract

Electrochemistry offers a variety of novel means by which selectivity can be introduced into synthetic organic transformations. In the work reported, it is shown how methods used to confine chemical reactions to specific sites on a microelectrode array can also be used to confine a preparative reaction to the surface of an electrode inserted into a bulk reaction solution. In so doing, the surface of a modified electrode can be used to introduce new selectivity into a preparative reaction that is not observed in the absence of either the modified electrode surface or the effort to confine the reaction to that surface. The observed selectivity can be optimized in the same way that confinement is optimized on an array and is dependent on the nature of the functionalized surface.

Indexed as

ElectrochemistryModified SurfacesOrganic SynthesisSelective Reactions

Identifiers

PMID34982848
PMCPMC8863644

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.