Evidence map›Paper›PMID 34978817›Full record

ArticleThe Journal of organic chemistry2022

Mechanistic Insights into the Formation of 1-Alkylidene/Arylidene-1,2,4-triazolinium Salts: A Combined NMR/Density Functional Theory Approach.

Johann Pann, Kevin Erharter, Daniel Langerreiter, Gabriel Partl, Thomas Müller, Herwig Schottenberger, Michael Hummel, Thomas S Hofer, Christoph Kreutz, Lukas Fliri

Abstract read
In one paragraph

Article in The Journal of organic chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Johann PannInstitute of General, Inorganic Chemistry and Theoretical Chemistry, Faculty of Chemistry and Pharmacy, University of Innsbruck, Innrain 80-82, 6020 Innsbruck, Austria.
Kevin ErharterInstitute of Organic Chemistry and Center for Molecular Bioscience Innsbruck (CMBI), Faculty of Chemistry and Pharmacy, University of Innsbruck, Innrain 80-82, 6020 Innsbruck, Austria.
Daniel LangerreiterDepartment of Bioproducts and Biosystems, Aalto University, P.O. Box 16300, 0076 Aalto, Finland.
Gabriel PartlInstitute of General, Inorganic Chemistry and Theoretical Chemistry, Faculty of Chemistry and Pharmacy, University of Innsbruck, Innrain 80-82, 6020 Innsbruck, Austria.
Thomas MüllerInstitute of Organic Chemistry and Center for Molecular Bioscience Innsbruck (CMBI), Faculty of Chemistry and Pharmacy, University of Innsbruck, Innrain 80-82, 6020 Innsbruck, Austria.ORCID https://orcid.org/0000-0002-3400-3248
Herwig SchottenbergerInstitute of General, Inorganic Chemistry and Theoretical Chemistry, Faculty of Chemistry and Pharmacy, University of Innsbruck, Innrain 80-82, 6020 Innsbruck, Austria.
Michael HummelDepartment of Bioproducts and Biosystems, Aalto University, P.O. Box 16300, 0076 Aalto, Finland.ORCID https://orcid.org/0000-0002-6982-031X
Thomas S HoferInstitute of General, Inorganic Chemistry and Theoretical Chemistry, Faculty of Chemistry and Pharmacy, University of Innsbruck, Innrain 80-82, 6020 Innsbruck, Austria.
Christoph KreutzInstitute of Organic Chemistry and Center for Molecular Bioscience Innsbruck (CMBI), Faculty of Chemistry and Pharmacy, University of Innsbruck, Innrain 80-82, 6020 Innsbruck, Austria.ORCID https://orcid.org/0000-0002-7018-9326
Lukas FliriInstitute of General, Inorganic Chemistry and Theoretical Chemistry, Faculty of Chemistry and Pharmacy, University of Innsbruck, Innrain 80-82, 6020 Innsbruck, Austria.ORCID https://orcid.org/0000-0001-5555-8659

Funding

Austrian Science Fund FWF P 34370
6 · The paper itself

Abstract

In a recent report on the synthetic approach to the novel substance class of 1-alkylidene/arylidene-1,2,4-triazolinium salts, a reaction mechanism suggesting a regioselective outcome was proposed. This hypothesis was tested via a combined NMR and density functional theory (DFT) approach. To this end, three experiments with

Identifiers

PMID34978817
PMCPMC8790756

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.