ReviewChemical reviews2022
Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.
Review in Chemical reviews, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed, 81 citations in OpenAlex.
- Si-O Bond Formation Mediated by an Osmium-Polyhydride: Dehydrogenative Silylation of Alcohols and Tandem Hydrosilylation/Dehydrogenative Silylation of Salicylaldehydes.Inorganic chemistry · 2026Article
- Unraveling the coordination isomerism by ligand hyperfine NMR shifts.Chemical science · 2026Article
- Catalytic aromatic C-H borylation via strained Si and Ge metallacycles.Nature communications · 2025Article
- Switchable electrochemical pathways for the selective C(spNature communications · 2025Article
- Synthesis of silylbut-1-en-3-ynes and buta-1,3-dienes as building blocks via hydrosilylation of 1,4-bis(trimethylsilyl)buta-1,3-diyne.Scientific reports · 2024Article
- Preparation of TScientific reports · 2024Article
- Catalytic Tetrazole Synthesis via [3+2] Cycloaddition of NaNACS omega · 2024Article
- Article
- Aluminum-Boron Bond Formation by Boron Ester Oxidative Addition at an Alumanyl Anion.Inorganic chemistry · 2023Article
- Functionalization of octaspherosilicate (HSiMeScientific reports · 2023Article
- Germanium hydrides as an efficient hydrogen-storage material operated by an iron catalyst.Chemical science · 2023Article
- Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between HChemical science · 2022Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
While the formation and breaking of transition metal (TM)-carbon bonds plays a pivotal role in the catalysis of organic compounds, the reactivity of inorganometallic species, that is, those involving the transition metal (TM)-metalloid (E) bond, is of key importance in most conversions of metalloid derivatives catalyzed by TM complexes. This Review presents the background of inorganometallic catalysis and its development over the last 15 years. The results of mechanistic studies presented in the Review are related to the occurrence of TM-E and TM-H compounds as reactive intermediates in the catalytic transformations of selected metalloids (E = B, Si, Ge, Sn, As, Sb, or Te). The Review illustrates the significance of inorganometallics in catalysis of the following processes: addition of metalloid-hydrogen and metalloid-metalloid bonds to unsaturated compounds; activation and functionalization of C-H bonds and C-X bonds with hydrometalloids and bismetalloids; activation and functionalization of C-H bonds with vinylmetalloids, metalloid halides, and sulfonates; and dehydrocoupling of hydrometalloids. This first Review on inorganometallic catalysis sums up the developments in the catalytic methods for the synthesis of organometalloid compounds and their applications in advanced organic synthesis as a part of tandem reactions.
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