ArticleACS central science2021
Closed-Loop Electrolyte Design for Lithium-Mediated Ammonia Synthesis.
Article in ACS central science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
13 citing papers in PubMed, 64 citations in OpenAlex.
- Pathways to sustainable lithium-mediated ammonia electrosynthesis: tuning reaction environment and advancing reactor design.RSC advances · 2026Review
- How to Efficiently Design 2D Materials for Electrochemical Applications Using Machine Learning.Precision chemistry · 2026Article
- In situ NMR-guided design of alkaline electrochemical ammonia synthesis.Science advances · 2025Article
- Toward Stable Li-Mediated Nitrogen Reduction: Strategies, Milestones, and Future Outlook.ChemSusChem · 2025Review
- Lattice-Nitrogen-Mediated Chemistry Suppresses Hydrogen Evolution for Record Faradaic Efficiency in Ammonia Synthesis.Journal of the American Chemical Society · 2025Article
- A carbon cathode for lithium mediated electrochemical ammonia synthesis.Energy & environmental science · 2025Article
- Localized High-Concentration Electrolyte in Li-Mediated Nitrogen Reduction for Ammonia Synthesis.Advanced materials (Deerfield Beach, Fla.) · 2024Article
- Regulating Interfacial Microenvironment in Aqueous Electrolyte via a NAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Phenol as proton shuttle and buffer for lithium-mediated ammonia electrosynthesis.Nature communications · 2024Article
- Searching for the Rules of Electrochemical Nitrogen Fixation.ACS catalysis · 2023Article
- Electrocatalytic Reduction of Dinitrogen to Ammonia with Water as Proton and Electron Donor Catalyzed by a Combination of a Tri-ironoxotungstate and an Alkali Metal Cation.Journal of the American Chemical Society · 2023Article
- Electrochemical Nitrogen Fixation for Green Ammonia: Recent Progress and Challenges.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Review
- Near ambient NNature reviews. Chemistry · 2023Review
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Novel methods for producing ammonia, a large-scale industrial chemical, are necessary for reducing the environmental impact of its production. Lithium-mediated electrochemical nitrogen reduction is one attractive alternative method for producing ammonia. In this work, we experimentally tested several classes of proton donors for activity in the lithium-mediated approach. From these data, an interpretable data-driven classification model is constructed to distinguish between active and inactive proton donors; solvatochromic Kamlet-Taft parameters emerged to be the key descriptors for predicting nitrogen reduction activity. A deep learning model is trained to predict these parameters using experimental data from the literature. The combination of the classification and deep learning models provides a predictive mapping from proton donor structure to activity for nitrogen reduction. We demonstrate that the two-model approach is superior to a purely mechanistic or a data-driven approach in accuracy and experimental data efficiency.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.