Evidence map›Paper›PMID 34960894›Full record

ArticlePolymers2021

Hydrogen Recovery by Mixed Matrix Membranes Made from 6FCl-APAF HPA with Different Contents of a Porous Polymer Network and Their Thermal Rearrangement.

Cenit Soto, Edwin S Torres-Cuevas, Alfonso González-Ortega, Laura Palacio, Pedro Prádanos, Benny D Freeman, Ángel E Lozano, Antonio Hernandez

Open access · goldAbstract read
In one paragraph

Article in Polymers, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
1.0field-weighted citation impact, top 26% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 11 citations in OpenAlex.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 2 institutions in 2 countries.

Cenit SotoSurfaces and Porous Materials (SMAP), Associated Research Unit to CSIC, Facultad de Ciencias, University of Valladolid, Paseo Belén 7, E-47011 Valladolid, Spain.ORCID 0000-0003-0799-8697
Edwin S Torres-CuevasMcKetta Department of Chemical Engineering, Texas Materials Institute, The University of Texas at Austin, 200 E Dean Keeton St., Austin, TX 78712, USA.ORCID 0000-0001-9098-4653
Alfonso González-OrtegaDepartment of Organic Chemistry, School of Sciences, Facultad de Ciencias, University of Valladolid, Paseo Belén 7, E-47011 Valladolid, Spain.
Laura PalacioSurfaces and Porous Materials (SMAP), Associated Research Unit to CSIC, Facultad de Ciencias, University of Valladolid, Paseo Belén 7, E-47011 Valladolid, Spain.ORCID 0000-0001-9886-9553
Pedro PrádanosSurfaces and Porous Materials (SMAP), Associated Research Unit to CSIC, Facultad de Ciencias, University of Valladolid, Paseo Belén 7, E-47011 Valladolid, Spain.ORCID 0000-0001-8939-8518
Benny D FreemanMcKetta Department of Chemical Engineering, Texas Materials Institute, The University of Texas at Austin, 200 E Dean Keeton St., Austin, TX 78712, USA.
Ángel E LozanoSurfaces and Porous Materials (SMAP), Associated Research Unit to CSIC, Facultad de Ciencias, University of Valladolid, Paseo Belén 7, E-47011 Valladolid, Spain.ORCID 0000-0003-4209-3842
Antonio HernandezSurfaces and Porous Materials (SMAP), Associated Research Unit to CSIC, Facultad de Ciencias, University of Valladolid, Paseo Belén 7, E-47011 Valladolid, Spain.
Universidad de Valladolid · ESThe University of Texas at Austin · US

Funding

Regional Government of Castilla y León and the EU-FEDER program CLU2017-09, UIC082, VA088G19Spanish Government (AEI) PID2019-109403RBC21/AEI/10.13039/501100011033, PID2019-109403RBC22/AEI/10.13039/501100011033 and EQC2019-006481-P
6 · The paper itself

Abstract

Mixed matrix membranes (MMMs) consisting of a blend of a hydroxypolyamide (HPA) matrix and variable loads of a porous polymer network (PPN) were thermally treated to induce the transformation of HPA to polybenzoxazole (β-TR-PBO). Here, the HPA matrix was a hydroxypolyamide having two hexafluoropropyilidene moieties, 6FCl-APAF, while the PPN was prepared by reacting triptycene (TRP) and trifluoroacetophenone (TFAP) in a superacid solution. The most probable size of the PPN particles was 75 nm with quite large distributions. The resulting membranes were analyzed by SEM and AFM. Up to 30% PPN loads, both SEM and AFM images confirmed quite planar surfaces, at low scale, with limited roughness. Membranes with high hydrogen permeability and good selectivity for the gas pairs H

Indexed as

gas separationhydrogen separationmixed matrix membranesporous polymer networkthermal rearrangement

Identifiers

PMID34960894
PMCPMC8703379
OpenAlexW4200299796

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.