Evidence map›Paper›PMID 34958698›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022

Understanding the Influence of Donor-Acceptor Diazo Compounds on the Catalyst Efficiency of B(C

Rasool Babaahmadi, Ayan Dasgupta, Christopher J T Hyland, Brian F Yates, Rebecca L Melen, Alireza Ariafard

Open access · hybridAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
1.5field-weighted citation impact, top 18% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 19 citations in OpenAlex.

  1. Properties of Bisdiazo Compounds and Their Derived Carbenes via Density Functional Theory.Chemphyschem : a European journal of chemical physics and physical chemistry · 2026
    Article
  2. Article
  3. Kinetics of NACS omega · 2024
    Article
  4. B(COrganic letters · 2023
    Article
  5. Article
  6. Article
  7. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 3 institutions in 3 countries.

Rasool BabaahmadiSchool of Natural Sciences (Chemistry), University of Tasmania, Private Bag 75, Hobart, Tasmania, 7001, Australia.ORCID http://orcid.org/0000-0002-2580-6217
Ayan DasguptaCardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, Cymru/Wales, UK.ORCID http://orcid.org/0000-0001-9945-8334
Christopher J T HylandSchool of Chemistry and Molecular Bioscience, Molecular Horizons Research Institute, University of Wollongong, Wollongong, New South Wales, 2522, Australia.ORCID http://orcid.org/0000-0002-9963-5924
Brian F YatesSchool of Natural Sciences (Chemistry), University of Tasmania, Private Bag 75, Hobart, Tasmania, 7001, Australia.
Rebecca L MelenCardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, Cymru/Wales, UK.ORCID http://orcid.org/0000-0003-3142-2831
Alireza AriafardSchool of Natural Sciences (Chemistry), University of Tasmania, Private Bag 75, Hobart, Tasmania, 7001, Australia.ORCID http://orcid.org/0000-0003-2383-6380
University of Tasmania · AUUniversity of Wales Institute Cardiff · SGUniversity of Wollongong · AU

Funding

Engineering and Physical Sciences Research Council EP/R026912/1
6 · The paper itself

Abstract

Diazo compounds have been largely used as carbene precursors for carbene transfer reactions in a variety of functionalization reactions. However, the ease of carbene generation from the corresponding diazo compounds depends upon the electron donating/withdrawing substituents either side of the diazo functionality. These groups strongly impact the ease of N

Indexed as

carbenedensity functional theory (DFT)diazo compoundsLewis acid catalysismechanistic studytris(pentafluorophenyl)borane

Identifiers

PMID34958698
PMCPMC9303686
OpenAlexW4200289690

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.