Versatile Covalent Postsynthetic Modification of Metal Organic Frameworks via Thermal Condensation for Fluoride Sensing in Waters.

Eugenio Hernan Otal, Manuela Leticia Kim, Yoshiyuki Hattori, Yu Kitazawa, Juan Paulo Hinestroza, Mutsumi Kimura

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Article in Bioengineering (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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Authors and funding

6 authors.

Eugenio Hernan OtalDepartment of Chemistry and Materials, Faculty of Textile Science and Technology, Shinshu University, Ueda 386-8567, Japan.ORCID 0000-0003-0801-854X

Manuela Leticia KimDepartment of Chemistry and Materials, Faculty of Textile Science and Technology, Shinshu University, Ueda 386-8567, Japan.ORCID 0000-0002-3253-2760

Yoshiyuki HattoriDepartment of Chemistry and Materials, Faculty of Textile Science and Technology, Shinshu University, Ueda 386-8567, Japan.

Yu KitazawaDepartment of Chemistry and Materials, Faculty of Textile Science and Technology, Shinshu University, Ueda 386-8567, Japan.

Juan Paulo HinestrozaDepartment of Fiber Science and Apparel Design, Cornell University, Ithaca, NY 14853, USA.ORCID 0000-0002-8534-1407

Mutsumi KimuraDepartment of Chemistry and Materials, Faculty of Textile Science and Technology, Shinshu University, Ueda 386-8567, Japan.ORCID 0000-0003-3050-8254

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Having access to safe drinking water is one of the 17 sustainable development goals defined by the United Nations (UN). However, many settlements around the globe have limited access to drinkable water due to non-anthropogenic pollution of the water sources. One of those pollutants is fluoride, which can induce major health problems. In this manuscript, we report on a post synthetic functionalization of metal organic frameworks for the sensing of fluoride in water. The proposed thermal condensation methodology allows for a high yield of functionalization using few steps, reducing reagent costs and generating minimal by-products. We identified a Rhodamine B functionalized Al-BDC-NH2 metal organic framework as one particularly suitable for fluoride detection in water.

Indexed as

drinking waterfluoridemetal organic frameworkspost-functionalizationsensorsthermal condensation

Identifiers

PMID34940349

DOI10.3390/bioengineering8120196

PMCPMC8698826

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