Evidence map›Paper›PMID 34936179›Full record

ArticleAngewandte Chemie (International ed. in English)2022

A General Access Route to High-Nuclearity, Metal-Functionalized Molecular Vanadium Oxides.

Simon Greiner, Jan Hettig, Alec Laws, Katharina Baumgärtner, Jenna Bustos, Ann-Christin Pöppler, Adam H Clark, May Nyman, Carsten Streb, Montaha Anjass

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Simon GreinerInstitute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Jan HettigInstitute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Alec LawsInstitute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Katharina BaumgärtnerInstitute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Jenna BustosDepartment of Chemistry, Oregon State University, Corvallis, OR 97331, USA.
Ann-Christin PöpplerInstitute of Organic Chemistry, University of Wuerzburg, Am Hubland, 97074, Wuerzburg, Germany.
Adam H ClarkPaul Scherrer Institute, Forschungsstraße 111, 5232, Villingen, Switzerland.
May NymanDepartment of Chemistry, Oregon State University, Corvallis, OR 97331, USA.
Carsten StrebInstitute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.ORCID http://orcid.org/0000-0002-5846-1905
Montaha AnjassInstitute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.

Funding

Alexander von Humboldt-StiftungBaden-Württemberg StiftungDeutsche Forschungsgemeinschaft STR1164/12; STR1164/14; 364549901; 390874152European Research Council 101002212Helmholtz-GemeinschaftMinisterium für Wissenschaft, Forschung und Kunst Baden-Württemberg
6 · The paper itself

Abstract

Molecular metal oxides are key materials in diverse fields like energy storage and conversion, molecular magnetism and as model systems for solid-state metal oxides. To improve their performance and increase the variety of accessible motifs, new synthetic approaches are necessary. Herein, we report a universal, new precursor to access different metal-functionalized polyoxovanadate (POV) clusters. The precursor is synthesized by a novel solid-state thermal treatment procedure. Solution-phase test reactions at room temperature and pressure show that reaction of the precursor with various metal nitrate salts gives access to a range of metal-functionalized POVs. The first nitrate-templated molecular calcium vanadate cluster is reported. We show that this precursor could open new access routes to POV components for molecular magnetism, energy technologies or catalysis.

Indexed as

PolyoxometalateSelf-assemblySupramolecularSynthesisVanadium oxide

Identifiers

PMID34936179
PMCPMC9302674

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.