ArticleAngewandte Chemie (International ed. in English)2022
Stabilization of Polyoxometalate Charge Carriers via Redox-Driven Nanoconfinement in Single-Walled Carbon Nanotubes.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- POMsDB: a QM derived molecular properties and parameters database for Polyoxometalates.Scientific data · 2026Article
- Rational Confinement of NiMoMicromachines · 2026Article
- Unique Structural Features of Polyoxometalates for Efficient Alkaline Hydrogen-Evolution Reaction.ChemSusChem · 2026Review
- Direct Conversion of Ethanol to Ethyl Acetate by Dynamic Polyoxometalate/Carbon Nanohorn Electrocatalytic Interfaces.Journal of the American Chemical Society · 2025Article
- Precision Synthesis of a Single Chain Polymorph of a 2D Solid within Single-Walled Carbon Nanotubes.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Electron-Sponge Nature of Polyoxometalates for Next-Generation Electrocatalytic Water Splitting and Nonvolatile Neuromorphic Devices.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Review
- Voltammetric Evidence of Proton Transport through the Sidewalls of Single-Walled Carbon Nanotubes.Journal of the American Chemical Society · 2023Article
- Host-Guest Chemistry in Boron Nitride Nanotubes: Interactions with Polyoxometalates and Mechanism of Encapsulation.Journal of the American Chemical Society · 2023Article
- Polyoxometalate steric hindrance driven chirality-selective separation of subnanometer carbon nanotubes.Chemical science · 2022Article
- Stabilization of Polyoxometalate Charge Carriers via Redox-Driven Nanoconfinement in Single-Walled Carbon Nanotubes.Angewandte Chemie (International ed. in English) · 2022Article
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Authors and funding
9 authors.
Funding
Abstract
We describe the preparation of hybrid redox materials based on polyoxomolybdates encapsulated within single-walled carbon nanotubes (SWNTs). Polyoxomolybdates readily oxidize SWNTs under ambient conditions in solution, and here we study their charge-transfer interactions with SWNTs to provide detailed mechanistic insights into the redox-driven encapsulation of these and similar nanoclusters. We are able to correlate the relative redox potentials of the encapsulated clusters with the level of SWNT oxidation in the resultant hybrid materials and use this to show that precise redox tuning is a necessary requirement for successful encapsulation. The host-guest redox materials described here exhibit exceptional electrochemical stability, retaining up to 86 % of their charge capacity over 1000 oxidation/reduction cycles, despite the typical lability and solution-phase electrochemical instability of the polyoxomolybdates we have explored. Our findings illustrate the broad applicability of the redox-driven encapsulation approach to the design and fabrication of tunable, highly conductive, ultra-stable nanoconfined energy materials.
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