ArticleAngewandte Chemie (International ed. in English)2022
Controlling Chemoselectivity of Catalytic Hydroboration with Light.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
5 citing papers in PubMed.
- Article
- Highlights from the 56th Bürgenstock Conference on Stereochemistry 2023.Chemical science · 2023Article
- Mild and Chemoselective Carboxylic Acid Reduction Promoted by Borane Catalysis.Angewandte Chemie (International ed. in English) · 2022Article
- An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes.Angewandte Chemie (International ed. in English) · 2022Article
- Controlling Chemoselectivity of Catalytic Hydroboration with Light.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
The ability to selectively react one functional group in the presence of another underpins efficient reaction sequences. Despite many designer catalytic systems being reported for hydroboration reactions, which allow introduction of a functional handle for cross-coupling or act as mild method for reducing polar functionality, these platforms rarely deal with more complex systems where multiple potentially reactive sites exist. Here we demonstrate, for the first time, the ability to use light to distinguish between ketones and carboxylic acids in more complex molecules. By taking advantage of different activation modes, a single catalytic system can be used for hydroboration, with the chemoselectivity dictated only by the presence or absence of visible light.
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Registered trials
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