ArticleAngewandte Chemie (International ed. in English)2022
Nitrogen Atom Transfer Catalysis by Metallonitrene C-H Insertion: Photocatalytic Amidation of Aldehydes.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed.
- Efficient COMolecules (Basel, Switzerland) · 2026Article
- A photogenerated triplet aura-nitrene for gold-mediated nitrene transfer.Nature chemistry · 2026Article
- Solid-state molecular organometallic chemistry (SMOM): a user guide toDalton transactions (Cambridge, England : 2003) · 2026Review
- Crystalline nitrogen chain radical anions.Nature chemistry · 2026Article
- Proton, Electron, and Hydrogen-Atom Transfer Thermodynamics of the Metal-Organic Framework, Ti-MIL-125, Are Intrinsically Correlated to the Structural Disorder.Journal of the American Chemical Society · 2025Article
- Historical and Recent Developments in the Chemistry of Cyanate Congeners.Inorganic chemistry · 2025Review
- Diverging Reactivity in Anilidophosphine Supported Group III Complexes.Chemistry, an Asian journal · 2025Article
- Review
- Catalytic Amino Group Transfer Reactions Mediated by Photoinduced Nitrene Formation from Rhodium-Hydroxamates.Angewandte Chemie (International ed. in English) · 2025Article
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- P-P CouplingJournal of the American Chemical Society · 2025Article
- Transient Triplet Metallopnictinidenes M-Pn (M = PdJournal of the American Chemical Society · 2025Article
- An Open-Shell FeJournal of the American Chemical Society · 2025Article
- Synthesis and electrochemical properties of molybdenum nitrido complexes supported by redox-active NHC and MIC ligands.Dalton transactions (Cambridge, England : 2003) · 2025Article
- A Lead(II) Substituted Triplet Carbene.Journal of the American Chemical Society · 2024Article
- Modular Synthesis of Monoanionic PN Ligands Leads to Unexpected Structural Diversity in Lanthanum Chemistry.Inorganic chemistry · 2024Article
- Article
- Photoinitiated Single-Crystal to Single-Crystal Redox Transformations of Titanium-Oxo Clusters.Journal of the American Chemical Society · 2024Article
- Untangling ancillary ligand donationChemical science · 2024Article
- Cationic Divalent Metal Sites (M = Mn, Fe, Co) Operating as Both Nitrene-Transfer Agents and Lewis Acids toward Mediating the Synthesis of Three- and Five-MemberedInorganic chemistry · 2023Article
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11 authors.
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Abstract
C-H amination and amidation by catalytic nitrene transfer are well-established and typically proceed via electrophilic attack of nitrenoid intermediates. In contrast, the insertion of (formal) terminal nitride ligands into C-H bonds is much less developed and catalytic nitrogen atom transfer remains unknown. We here report the synthesis of a formal terminal nitride complex of palladium. Photocrystallographic, magnetic, and computational characterization support the assignment as an authentic metallonitrene (Pd-N) with a diradical nitrogen ligand that is singly bonded to Pd
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