Evidence map›Paper›PMID 34900942›Full record

ArticleFrontiers in chemistry2021

Basicity as a Thermodynamic Descriptor of Carbanions Reactivity with Carbon Dioxide: Application to the Carboxylation of α,β-Unsaturated Ketones.

Pietro Franceschi, Catia Nicoletti, Ruggero Bonetto, Marcella Bonchio, Mirco Natali, Luca Dell'Amico, Andrea Sartorel

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Frontiers in chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
0.2field-weighted citation impact, top 58% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 7 citations in OpenAlex.

  1. Discovering COJournal of chemical information and modeling · 2026
    Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 2 institutions in 1 country.

Pietro FranceschiNano and Molecular Catalysis Laboratory, Department of Chemical Sciences, University of Padova, Padova, Italy.
Catia NicolettiNano and Molecular Catalysis Laboratory, Department of Chemical Sciences, University of Padova, Padova, Italy.
Ruggero BonettoNano and Molecular Catalysis Laboratory, Department of Chemical Sciences, University of Padova, Padova, Italy.
Marcella BonchioNano and Molecular Catalysis Laboratory, Department of Chemical Sciences, University of Padova, Padova, Italy.
Mirco NataliDepartment of Chemical, Pharmaceutical and Agricultural Sciences (DOCPAS), University of Ferrara, and Centro Interuniversitario per La Conversione Chimica Dell'Energia Solare (SOLARCHEM), Ferrara, Italy.
Luca Dell'AmicoNano and Molecular Catalysis Laboratory, Department of Chemical Sciences, University of Padova, Padova, Italy.
Andrea SartorelNano and Molecular Catalysis Laboratory, Department of Chemical Sciences, University of Padova, Padova, Italy.
University of Padua · ITUniversity of Ferrara · IT

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The utilization of carbon dioxide as a raw material represents nowadays an appealing strategy in the renewable energy, organic synthesis, and green chemistry fields. Besides reduction strategies, carbon dioxide can be exploited as a single-carbon-atom building block through its fixation into organic scaffolds with the formation of new C-C bonds (carboxylation processes). In this case, activation of the organic substrate is commonly required, upon formation of a carbanion C

Indexed as

carbon dioxide fixationDFT calculationsreaction intermediatesthermodynamic analysisunsaturated carbonyl

Identifiers

PMID34900942
PMCPMC8652261
OpenAlexW3217215608

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.