ArticleNature communications2021
Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
6 citing papers in PubMed.
- Structural Analysis of Curium, Promethium, and Early Lanthanides Using 2,2':6',2″-Terpyridine in the Presence of Acid.Inorganic chemistry · 2026Article
- Bonding and reactivity of isostructural uranyl and neptunyl peroxide phases.Communications chemistry · 2025Article
- Probing the subtle differences between promethium and curium.Nature communications · 2025Article
- On the origin of low-valent uranium oxidation state.Nature communications · 2024Article
- Polyoxometalate Ligands Reveal Different Coordination Chemistries Among Lanthanides and Heavy Actinides.JACS Au · 2024Article
- Isolation of a californium(II) crown-ether complex.Nature chemistry · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
18 authors.
Funding
Abstract
Controlling the properties of heavy element complexes, such as those containing berkelium, is challenging because relativistic effects, spin-orbit and ligand-field splitting, and complex metal-ligand bonding, all dictate the final electronic states of the molecules. While the first two of these are currently beyond experimental control, covalent M‒L interactions could theoretically be boosted through the employment of chelators with large polarizabilities that substantially shift the electron density in the molecules. This theory is tested by ligating Bk
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.