ArticleJournal of the American Chemical Society2021
Preparation of Recyclable and Versatile Porous Poly(aryl thioether)s by Reversible Pd-Catalyzed C-S/C-S Metathesis.
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- C─S Bond Metathesis Reactions: Concepts, Scope, and Mechanistic Insight.Chemistry, an Asian journal · 2026Review
- Crystal structure and Hirshfeld surface analysis of 3,3'-(sulfanedi-yl)bis-(2-iodo-1-methyl-1Acta crystallographica. Section E, Crystallographic communications · 2026Article
- Sulfur-containing sustainable polymers: synthetic pathways, degradation mechanisms, and multifunctional applications.National science review · 2025Review
- Understanding and Controlling Reactivity Patterns of PdACS catalysis · 2024Article
- Heterogeneously catalyzed thioether metathesis by a supported Au-Pd alloy nanoparticle design based on Pd ensemble control.Chemical science · 2024Article
- Indomuscone-Based Sterically Encumbered Phosphines as Ligands for Palladium-Catalyzed Reactions.The Journal of organic chemistry · 2023Article
- Ring-closing C-O/C-O metathesis of ethers with primary aliphatic alcohols.Nature communications · 2023Article
- Electron-Poor Phosphines Enable the Selective Semihydrogenation Reaction of Alkynes with Pd on Carbon Catalysts.The journal of physical chemistry letters · 2023Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Porous organic materials (polymers and COFs) have shown a number of promising properties; however, the lability of their linkages often limits their robustness and can hamper downstream industrial application. Inspired by the outstanding chemical, mechanical, and thermal resistance of the 1D polymer poly(phenylene sulfide) (PPS), we have designed a new family of porous poly(aryl thioether)s, synthesized via a mild Pd-catalyzed C-S/C-S metathesis-based method, that merges the attractive features common to porous polymers and PPS in a single material. In addition, the method is highly modular, allowing to easily introduce application-oriented functionalities in the materials for a series of environmentally relevant applications including metal capture, metal sensing, and heterogeneous catalysis. Moreover, despite their extreme chemical resistance, the polymers can be easily recycled to recover the original monomers, offering an attractive perspective for their sustainable use. In a broader context, these results clearly demonstrate the untapped potential of emerging single-bond metathesis reactions in the preparation of new, recyclable materials.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.