Evidence map›Paper›PMID 34868598›Full record

ArticleOrganic chemistry frontiers : an international journal of organic chemistry2021

Unusual Rearrangement-Remercuration Reactions of Allylic Silanols.

Someshwar Nagamalla, Ranjeet A Dhokale, Frederick J Seidl, Joel T Mague, Shyam Sathyamoorthi

Open access · greenAbstract read
In one paragraph

Article in Organic chemistry frontiers : an international journal of organic chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.

0numbers the graph read from it
0cells of the map it votes in
13citing papers in PubMed
1.3field-weighted citation impact, top 22% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

13 citing papers in PubMed, 14 citations in OpenAlex.

  1. Article
  2. Large-Scale Syntheses of Silanoxy-TetrahydrofuransOrganic syntheses; an annual publication of satisfactory methods for the preparation of organic chemicals · 2025
    Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Large Scale Epoxide Opening by a Pendant Silanol.Organic syntheses; an annual publication of satisfactory methods for the preparation of organic chemicals · 2023
    Article
  10. Article
  11. Highly Stereospecific Cyclizations of Homoallylic Silanols.The Journal of organic chemistry · 2022
    Article
  12. Article
  13. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 3 institutions in 1 country.

Someshwar NagamallaDepartment of Medicinal Chemistry, University of Kansas, Lawrence, Kansas, United States, 66047.
Ranjeet A DhokaleDepartment of Medicinal Chemistry, University of Kansas, Lawrence, Kansas, United States, 66047.
Frederick J SeidlIndependent Researcher, San Mateo, California, United States, 94402.
Joel T MagueDepartment of Chemistry, Tulane University, New Orleans, Louisiana, United States, 70118.
Shyam SathyamoorthiDepartment of Medicinal Chemistry, University of Kansas, Lawrence, Kansas, United States, 66047.
University of Kansas · USCollege of San Mateo · USTulane University · US

Funding

Synthetic Chemical Biology CoreP20GM113117 · NIGMS · UNIVERSITY OF KANSAS LAWRENCE · PI OROZCO, ROBIN C. · 2016 to 2025
$23.9M
NIGMS NIH HHS P20 GM113117
6 · The paper itself

Abstract

We present the first examples of rearrangement reactions of allylic silanol substrates into linear ketone and 5-membered cyclic silanediol organomercurial products. Both reactions are mediated by Hg(OTf)

Identifiers

PMID34868598
PMCPMC8635418
OpenAlexW3190446991

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.