ArticleNano-micro letters2021
Precise Thermoplastic Processing of Graphene Oxide Layered Solid by Polymer Intercalation.
Article in Nano-micro letters, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Solvent-free thermoplastic foaming for superelastic graphene monoliths.Nature communications · 2025Article
- Monodomain Liquid Crystals of Two-Dimensional Sheets by Boundary-Free Sheargraphy.Nano-micro letters · 2022Article
- Emerging Flexible Thermally Conductive Films: Mechanism, Fabrication, Application.Nano-micro letters · 2022Review
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Authors and funding
13 authors.
Funding
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Abstract
The processing capability is vital for the wide applications of materials to forge structures as-demand. Graphene-based macroscopic materials have shown excellent mechanical and functional properties. However, different from usual polymers and metals, graphene solids exhibit limited deformability and processibility for precise forming. Here, we present a precise thermoplastic forming of graphene materials by polymer intercalation from graphene oxide (GO) precursor. The intercalated polymer enables the thermoplasticity of GO solids by thermally activated motion of polymer chains. We detect a critical minimum containing of intercalated polymer that can expand the interlayer spacing exceeding 1.4 nm to activate thermoplasticity, which becomes the criteria for thermal plastic forming of GO solids. By thermoplastic forming, the flat GO-composite films are forged to Gaussian curved shapes and imprinted to have surface relief patterns with size precision down to 360 nm. The plastic-formed structures maintain the structural integration with outstanding electrical (3.07 × 10
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