ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Solution Phase Reactivity of Dibenzo[c,e][1,2]azaborinine: Activation and Insertion into Si-E Single Bonds (E=H, OSi(CH
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Phenylpyridine-Based Boron Azides: Tuning Reactivity and Accessing Fluorescent Triazoles.Inorganic chemistry · 2025Article
- A Nitrilium-TypeJournal of the American Chemical Society · 2025Article
- Strain induced reactivity of cyclic iminoboranes: the (2 + 2) cycloaddition of a 1Chemical science · 2024Article
- Solution Phase Reactivity of Dibenzo[c,e][1,2]azaborinine: Activation and Insertion into Si-E Single Bonds (E=H, OSi(CHChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
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Authors and funding
4 authors.
Funding
Abstract
The boron-nitrogen analogue of ortho-benzyne, 1,2-azaborinine, is a reactive intermediate that features a formal boron-nitrogen triple bond. We here show by combining experimental and computational techniques that the Lewis acidity of the boron center of dibenzo[c,e][1,2]azaborinine allows interaction with the silicon containing single bonds Si-E through the silicon bonding partner E (E=F, Cl, OR, H). The binding to boron activates the Si-E bonds for subsequent insertion reaction. This shows that the BN-aryne is a ferocious species that even can activate and insert into the very strong Si-F bond.
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