ArticleOrganic letters2021
Stereocontrolled Synthesis and Structural Revision of Plebeianiol A.
Article in Organic letters, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Cobalt catalysis in organic synthesis: a powerful tool in the synthesis of natural products and pharmaceutically active compounds.RSC advances · 2026Review
- Selective isomerization of 2,3-disubstituted butanediacetal esters and thioesters using lithium and sodium enolates: effects of bases and additives on stereoselectivity.Frontiers in chemistry · 2026Article
- Unexpected Regiochemical Control in the Nugent-RajanBabu Reductive Epoxide Cyclization.Synthesis · 2025Article
- Directed Hydrogen Atom Transfer for Selective Reactions of Polyenols.Journal of the American Chemical Society · 2024Article
- Unified short syntheses of oxygenated tricyclic aromatic diterpenes by radical cyclization with a photoredox catalyst.Communications chemistry · 2023Article
- Synthesis of a Complex Brasilicardin Analogue Utilizing a Cobalt-Catalyzed MHAT-Induced Radical Bicyclization Reaction.Organic letters · 2023Article
- Hydrogen-Atom-Transfer-Initiated Radical/Polar Crossover Annulation Cascade for Expedient Access to Complex Tetralins.Angewandte Chemie (International ed. in English) · 2023Article
- Programmed Polyene Cyclization Enabled by Chromophore Disruption.Journal of the American Chemical Society · 2022Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
We report the structural revision via synthesis of the abietane diterpenoid plebeianiol A. The synthesis was accomplished by a short and convergent sequence that featured our previously established cobalt-catalyzed hydrogen-atom-transfer-induced radical bicyclization. We further connected plebeianiol A as the likely biogenetic precursor to another previously reported ether-bridged abietane. Finally, we demonstrated that the key cyclization event is efficient with the A-ring diol protected as two different cyclic acetals or in unprotected form.
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Registered trials
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