Evidence map›Paper›PMID 34847330›Full record

ArticleInorganic chemistry2021

In-Depth Studies of Ground- and Excited-State Properties of Re(I) Carbonyl Complexes Bearing 2,2':6',2″-Terpyridine and 2,6-Bis(pyrazin-2-yl)pyridine Coupled with π-Conjugated Aryl Chromophores.

Agata Szlapa-Kula, Magdalena Małecka, Anna M Maroń, Henryk Janeczek, Mariola Siwy, Ewa Schab-Balcerzak, Marcin Szalkowski, Sebastian Maćkowski, Tomasz Pedzinski, Karol Erfurt and 1 more

Abstract read
In one paragraph

Article in Inorganic chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.

0numbers the graph read from it
0cells of the map it votes in
12citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

12 citing papers in PubMed.

  1. Article
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  5. Article
  6. Article
  7. Review
  8. Pyrenyl-Substituted Imidazo[4,5-Inorganic chemistry · 2023
    Article
  9. Article
  10. Article
  11. Article
  12. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Agata Szlapa-KulaInstitute of Chemistry, University of Silesia, ninth Szkolna Str., 40-006 Katowice, Poland.ORCID https://orcid.org/0000-0001-6539-5419
Magdalena MałeckaInstitute of Chemistry, University of Silesia, ninth Szkolna Str., 40-006 Katowice, Poland.
Anna M MarońInstitute of Chemistry, University of Silesia, ninth Szkolna Str., 40-006 Katowice, Poland.ORCID https://orcid.org/0000-0001-8245-5532
Henryk JaneczekCentre of Polymer and Carbon Materials, Polish Academy of Sciences, 34 M. Curie-Sklodowska Str., 41-819 Zabrze, Poland.
Mariola SiwyCentre of Polymer and Carbon Materials, Polish Academy of Sciences, 34 M. Curie-Sklodowska Str., 41-819 Zabrze, Poland.
Ewa Schab-BalcerzakCentre of Polymer and Carbon Materials, Polish Academy of Sciences, 34 M. Curie-Sklodowska Str., 41-819 Zabrze, Poland.ORCID https://orcid.org/0000-0002-7219-8664
Marcin SzalkowskiInstitute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University, 5 Grudziadzka Str., 87-100 Toruń, Poland.
Sebastian MaćkowskiInstitute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University, 5 Grudziadzka Str., 87-100 Toruń, Poland.ORCID https://orcid.org/0000-0003-1560-6315
Tomasz PedzinskiFaculty of Chemistry, Adam Mickiewicz University in Poznań, 89b Umultowska, 61-614 Poznań, Poland.ORCID https://orcid.org/0000-0002-4765-6264
Karol ErfurtDepartment of Chemical Organic Technology and Petrochemistry, Silesian University of Technology, Krzywoustego 4, 44-100 Gliwice, Poland.
Barbara MachuraInstitute of Chemistry, University of Silesia, ninth Szkolna Str., 40-006 Katowice, Poland.ORCID https://orcid.org/0000-0001-7688-6491

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

In the current work, comprehensive photophysical and electrochemical studies were performed for eight rhenium(I) complexes incorporating 2,2':6',2″-terpyridine (terpy) and 2,6-bis(pyrazin-2-yl)pyridine (dppy) with appended 1-naphthyl-, 2-naphthyl-, 9-phenanthrenyl, and 1-pyrenyl groups. Naphthyl and phenanthrenyl substituents marginally affected the energy of the MLCT absorption and emission bands, signaling a weak electronic coupling of the appended aryl group with the Re(I) center. The triplet MLCT state in these complexes is so low lying relative to the triplet

Identifiers

PMID34847330
PMCPMC8693190

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.