Evidence map›Paper›PMID 34825766›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Vectorial Catalysis in Surface-Anchored Nanometer-Sized Metal-Organic Frameworks-Based Microfluidic Devices.

Anna Lisa Semrau, Philip M Stanley, Dominik Huber, Michael Schuster, Bauke Albada, Han Zuilhof, Mirza Cokoja, Roland A Fischer

Abstract read
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In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Anna Lisa SemrauDepartment of Chemistry, Inorganic and Metal-Organic Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85787, Garching, Germany.ORCID 0000-0001-7087-932X
Philip M StanleyDepartment of Chemistry, Inorganic and Metal-Organic Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85787, Garching, Germany.ORCID 0000-0002-1951-4074
Dominik HuberDepartment of Chemistry, Analytical Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85787, Garching, Germany.ORCID 0000-0003-1808-1198
Michael SchusterDepartment of Chemistry, Analytical Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85787, Garching, Germany.
Bauke AlbadaLaboratory of Organic Chemistry, Wageningen University and Research, Stippeneng 4, 6708WE, Wageningen, The Netherlands.ORCID 0000-0003-3659-2434
Han ZuilhofLaboratory of Organic Chemistry, Wageningen University and Research, Stippeneng 4, 6708WE, Wageningen, The Netherlands.ORCID 0000-0001-5773-8506
Mirza CokojaDepartment of Chemistry, Inorganic and Metal-Organic Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85787, Garching, Germany.ORCID 0000-0003-3144-4678
Roland A FischerDepartment of Chemistry, Inorganic and Metal-Organic Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85787, Garching, Germany.ORCID 0000-0002-7532-5286

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Vectorial catalysis-controlling multi-step reactions in a programmed sequence and by defined spatial localization in a microscale device-is an enticing goal in bio-inspired catalysis research. However, translating concepts from natural cascade biocatalysis into artificial hierarchical chemical systems remains a challenge. Herein, we demonstrate integration of two different surface-anchored nanometer-sized metal-organic frameworks (MOFs) in a microfluidic device for modelling vectorial catalysis. Catalyst immobilization at defined sections along the microchannel and a two-step cascade reaction was conducted with full conversion after 30 seconds and high turnover frequencies (TOF≈10

Indexed as

CatalysisMetal-organic frameworksMicrofluidic devicesSurface anchoringVectorial catalysis

Identifiers

PMID34825766
PMCPMC9300199

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.