ArticleAngewandte Chemie (International ed. in English)2022
Biasing the Hierarchy Motifs of Nanotoroids: from 1D Nanotubes to 2D Porous Networks.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
8 citing papers in PubMed.
- Light-regulated templated self-assembly of bilayered nanotoroids.Chemical science · 2026Article
- Curvature-emergent supramolecular polymerization of a porphyrin dyad with a scissor-shaped motif.Chemical science · 2026Article
- Light-controlled smart materials: Supramolecular regulation and applications.Smart molecules : open access · 2024Review
- Self-assembly of cyclic peptide monolayers by hydrophobic supramolecular hinges.Chemical science · 2023Article
- Solvent-dependent self-assembly ofChemical science · 2023Article
- Fine-tuning of the size of supramolecular nanotoroids suppresses the subsequent catenation of nano-[2]catenane.Chemical science · 2023Article
- Photo-modulation of supramolecular polymorphism in the self-assembly of a scissor-shaped azobenzene dyad into nanotoroids and fibers.Chemical science · 2022Article
- Biasing the Hierarchy Motifs of Nanotoroids: from 1D Nanotubes to 2D Porous Networks.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Hierarchical organization of self-assembled structures into superstructures is omnipresent in Nature but has been rarely achieved in synthetic molecular assembly due to the absence of clear structural rules. We herein report on the self-assembly of scissor-shaped azobenzene dyads which form discrete nanotoroids that further organize into 2D porous networks. The steric demand of the peripheral aliphatic units diminishes the trend of the azobenzene dyad to constitute stackable nanotoroids in solution, thus affording isolated (unstackable) nanotoroids upon cooling. Upon drying, these nanotoroids organize at graphite surface to form well-defined 2D porous networks. The photoirradiation with UV and visible light enabled reversible dissociation and reconstruction of nanotoroids through the efficient trans↔cis isomerization of azobenzene moieties in solution.
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Registered trials
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