ArticleNature communications2021
Intrareticular charge transfer regulated electrochemiluminescence of donor-acceptor covalent organic frameworks.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
23 citing papers in PubMed, 184 citations in OpenAlex.
- Solid-state electrochemiluminescence sensor based on functional covalent organic frameworks for detecting CoMikrochimica acta · 2026Article
- Mechanistic insights into electrochemiluminescence: fueling advances in bioanalysis and imaging.Chemical science · 2026Review
- Synthesis of Two Oligocarbazoles Enabling Efficient Dopamine Detection.Precision chemistry · 2026Article
- Breaking the catalysis-quenching dilemma in covalent organic frameworks with metal single-atom sites for enhanced electrochemiluminescence.Nature communications · 2026Article
- Recent Proceedings of Advanced Electrochemiluminescence Imaging Technology and Applications in Accurate Analysis.Chemical & biomedical imaging · 2026Review
- Donor-acceptor covalent adaptable networks.Nature communications · 2026Article
- COFs in Action: Advanced Approaches for Monitoring Uranium, Mercury, Lead, and Nitro Compounds in Environmental Contaminants.Topics in current chemistry (Cham) · 2026Review
- Recent advances in aptamer-integrated covalent organic frameworks for electrochemiluminescence detection of emerging pollutants.iScience · 2026Review
- Weak localized electrons enhance electronic coherence for efficient photocatalytic uranium removal from nuclear wastewater.Nature communications · 2026Article
- Visualizing Single Molecular Crystals by Electrochemiluminescence Microscopy.Chemical & biomedical imaging · 2026Article
- Computational Modeling of Reticular Materials: The Past, the Present, and the Future.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Rational Design of Covalent Organic Frameworks for Enhanced Reticular Electrochemiluminescence and Biosensing Applications.Biosensors · 2025Review
- Tuning Core Flexibility and Curvature in Azine-Linked Covalent Organic Frameworks for Attomolar-Level Impedimetric Sensing of Glucose.Journal of the American Chemical Society · 2025Article
- Donor-acceptor type covalent organic frameworks: design, optimization strategies and applications.Chemical science · 2025Review
- Deciphering a volcano-shaped relationship between radical stability and reticular electrochemiluminescence.Nature communications · 2025Article
- Diacetylene-bridged covalent organic framework as crystalline graphdiyne analogue for photocatalytic hydrogen evolution.Chemical science · 2025Article
- Recent progress on charge transfer engineering in reticular framework for efficient electrochemiluminescence.Analytical and bioanalytical chemistry · 2024Review
- Switchable Site-Selective Benzanilide C(spMolecules (Basel, Switzerland) · 2024Article
- Robust links in photoactive covalent organic frameworks enable effective photocatalytic reactions under harsh conditions.Nature communications · 2024Article
- Luminescent Metal-Organic Frameworks for Electrochemiluminescent Detection of Water Pollutants.Materials (Basel, Switzerland) · 2023Review
Corrections and comments
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Authors and funding
10 authors at 2 institutions in 2 countries.
Funding
Abstract
The control of charge transfer between radical anions and cations is a promising way for decoding the emission mechanism in electrochemiluminescence (ECL) systems. Herein, a type of donor-acceptor (D-A) covalent organic framework (COF) with triphenylamine and triazine units is designed as a highly efficient ECL emitter with tunable intrareticular charge transfer (IRCT). The D-A COF demonstrates 123 folds enhancement in ECL intensity compared with its benzene-based COF with small D-A contrast. Further, the COF's crystallinity- and protonation-modulated ECL behaviors confirm ECL dependence on intrareticular charge transfer between donor and acceptor units, which is rationalized by density functional theory. Significantly, dual-peaked ECL patterns of COFs are achieved through an IRCT mediated competitive oxidation mechanism: the coreactant-mediated oxidation at lower potential and the direct oxidation at higher potential. This work provides a new fundamental and approach to improve the ECL efficiency for designing next-generation ECL devices.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.