ArticleJournal of the American Chemical Society2021
Overhauser Dynamic Nuclear Polarization with Selectively Deuterated BDPA Radicals.
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 26 papers.
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Who cites it
26 citing papers in PubMed, 56 citations in OpenAlex.
- High-frequency dynamic nuclear polarization in rotating solids.Science advances · 2026Review
- 14.1 T Liquid-StateJournal of the American Chemical Society · 2026Article
- Dynamic nuclear polarization and chemically induced hyperpolarization: Progress, mechanisms, and opportunities.Magnetic resonance letters · 2025Review
- Perspectives on the Dynamic Nuclear Polarization Mechanisms of Monoradicals: Overhauser Effect or Thermal Mixing?The journal of physical chemistry letters · 2025Review
- Proton hyperfine couplings and Overhauser DNP.Journal of magnetic resonance (San Diego, Calif. : 1997) · 2024Article
- Dipolar Recoupling in Rotating Solids.Chemical reviews · 2024Review
- Dynamic Nuclear Polarization with P1 Centers in Diamond.The journal of physical chemistry letters · 2024Article
- Mechanism of Solid-StateThe journal of physical chemistry letters · 2024Article
- Halogenated-edge polymeric semiconductor for efficient spin transport.Nature communications · 2024Article
- Detecting biomarkers by dynamic nuclear polarization enhanced magnetic resonance.National science review · 2024Review
- Cryogenic and Dissolution DNP NMR on γ-Irradiated Organic Molecules.Journal of the American Chemical Society · 2024Article
- Dipolar Order Induced Electron Spin Hyperpolarization.The journal of physical chemistry letters · 2024Article
- Multi Electron Spin Cluster Enabled Dynamic Nuclear Polarization with Sulfonated BDPA.The journal of physical chemistry letters · 2023Article
- Resonant Mixing Dynamic Nuclear Polarization.The journal of physical chemistry letters · 2023Article
- Frequency-swept dynamic nuclear polarization.Journal of magnetic resonance (San Diego, Calif. : 1997) · 2023Article
- Polarizing agents for efficient high field DNP solid-state NMR spectroscopy under magic-angle spinning: from design principles to formulation strategies.Chemical science · 2023Review
- Frontiers in the Application of RF Vacuum Electronics.IEEE transactions on electron devices · 2023Article
- PyrroTriPol: a semi-rigid trityl-nitroxide for high field dynamic nuclear polarization.Chemical science · 2023Article
- Dynamic nuclear polarization with trityl radicals.Journal of magnetic resonance (San Diego, Calif. : 1997) · 2023Article
- Spin Hyperpolarization in Modern Magnetic Resonance.Chemical reviews · 2023Review
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Authors and funding
8 authors at 2 institutions in 1 country.
Funding
Abstract
The Overhauser effect (OE), commonly observed in NMR spectra of liquids and conducting solids, was recently discovered in insulating solids doped with the radical 1,3-bisdiphenylene-2-phenylallyl (BDPA). However, the mechanism of polarization transfer in OE-DNP in insulators is yet to be established, but hyperfine coupling of the radical to protons in BDPA has been proposed. In this paper we present a study that addresses the role of hyperfine couplings via the EPR and DNP measurements on some selectively deuterated BDPA radicals synthesized for this purpose. Newly developed synthetic routes enable selective deuteration at orthogonal positions or perdeuteration of the fluorene moieties with
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.