ArticleNature communications2021
Resolving sub-angstrom ambient motion through reconstruction from vibrational spectra.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Nanoscale greenhouse effect for promoting solar-driven CONature communications · 2026Article
- Supramolecular Stabilization of Single-Molecule SERS: Cucurbit[7]uril Encapsulation of Thionine.ACS physical chemistry Au · 2026Article
- Generative design of functional organic molecules for terahertz radiation detection.Digital discovery · 2025Article
- Optical control of single-atom dynamics in plasmonic nanogaps.Science advances · 2025Article
- The Electric Field Morphology of Plasmonic Picocavities.Nano letters · 2025Article
- Article
- Alchemically-glazed plasmonic nanocavities using atomic layer metals: controllably synergizing catalysis and plasmonics.Nature communications · 2025Article
- Electronically Perturbed Vibrational Excitations of the Luminescing Stable Blatter Radical.ACS nano · 2025Article
- Nanocavities for Molecular Optomechanics: Their Fundamental Description and Applications.ACS photonics · 2024Review
- Impact of Surface Enhanced Raman Spectroscopy in Catalysis.ACS nano · 2024Review
- Directional picoantenna behavior of tunnel junctions formed by an atomic-scale surface defect.Science advances · 2024Article
- Uncovering low-frequency vibrations in surface-enhanced Raman of organic molecules.Nature communications · 2024Article
- High performance mechano-optoelectronic molecular switch.Nature communications · 2023Article
- Mapping Atomic-Scale Metal-Molecule Interactions: Salient Feature Extraction through Autoencoding of Vibrational Spectroscopy Data.The journal of physical chemistry letters · 2023Article
- A Full Quantum Mechanical Approach Assessing the Chemical and Electromagnetic Effect in TERS.ACS nano · 2023Article
- Article
- Machine learning of spectra-property relationship for imperfect and small chemistry data.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Picocavities: a Primer.Nano letters · 2022Article
- Optical suppression of energy barriers in single molecule-metal binding.Science advances · 2022Article
- Tracking interfacial single-molecule pH and binding dynamics via vibrational spectroscopy.Science advances · 2021Article
Corrections and comments
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Authors and funding
11 authors.
Funding
Abstract
Metal/organic-molecule interactions underpin many key chemistries but occur on sub-nm scales where nanoscale visualisation techniques tend to average over heterogeneous distributions. Single molecule imaging techniques at the atomic scale have found it challenging to track chemical behaviour under ambient conditions. Surface-enhanced Raman spectroscopy can optically monitor the vibrations of single molecules but understanding is limited by the complexity of spectra and mismatch between theory and experiment. We demonstrate that spectra from an optically generated metallic adatom near a molecule of interest can be inverted into dynamic sub-Å metal-molecule interactions using a comprehensive model, revealing anomalous diffusion of a single atom. Transient metal-organic coordination bonds chemically perturb molecular functional groups > 10 bonds away. With continuous improvements in computational methods for modelling large and complex molecular systems, this technique will become increasingly applicable to accurately tracking more complex chemistries.
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Registered trials
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