Evidence map›Paper›PMID 34796599›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Bimetallic Two-Dimensional Metal-Organic Frameworks for the Chemiresistive Detection of Carbon Monoxide.

Aylin Aykanat, Zheng Meng, Robert M Stolz, Colin T Morrell, Katherine A Mirica

Open access · greenAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.

0numbers the graph read from it
0cells of the map it votes in
22citing papers in PubMed
5.0field-weighted citation impact, top 4% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

22 citing papers in PubMed, 80 citations in OpenAlex.

  1. Review
  2. Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Article
  10. Article
  11. Review
  12. Review
  13. Article
  14. Review
  15. Article
  16. Research Progress on Chemiresistive Carbon Monoxide Sensors.Nanomaterials (Basel, Switzerland) · 2025
    Review
  17. Article
  18. Article
  19. A Dye-Sensitized Sensor for Oxygen Detection under Visible Light.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024
    Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 1 institution in 1 country.

Aylin AykanatLaboratory, Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA.
Zheng MengLaboratory, Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA.
Robert M StolzLaboratory, Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA.
Colin T MorrellLaboratory, Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA.
Katherine A MiricaLaboratory, Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA.ORCID 0000-0002-1779-7568
Dartmouth College · US

Funding

Chemically Precise Framework Materials as a Modular Platform Technology for ElectroanalysisR35GM138318 · NIGMS · DARTMOUTH COLLEGE · PI MIRICA, KATHERINE ANDREA · 2020 to 2024
$2.0M
Alfred P. Sloan Foundation FG-2018-10561Army Research Office W911NF-17-1-0398Camille and Henry Dreyfus FoundationCLC NIH HHS C0000008Cold Regions Research and Engineering Laboratory W913E519C0008National Science Foundation 1757371National Science Foundation 1945218NIGMS NIH HHS R35 GM138318NIH HHS R35GM138318Research Corporation for Science Advancement 26019
6 · The paper itself

Abstract

This paper describes the demonstration of a series of heterobimetallic, isoreticular 2D conductive metal-organic frameworks (MOFs) with metallophthalocyanine (MPc, M=Co and Ni) units interconnected by Cu nodes towards low-power chemiresistive sensing of ppm levels of carbon monoxide (CO). Devices achieve a sub-part-per-million (ppm) limit of detection (LOD) of 0.53 ppm toward CO at a low driving voltage of 0.1 V. MPc-based Cu-linked MOFs can continuously detect CO at 50 ppm, the permissible exposure limit required by the Occupational Safety and Health Administration (OSHA), for multiple exposures, and realize CO detection in air and in humid environment. Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), density functional theory (DFT) calculations, and comparison experiments suggest the contribution of Cu nodes to CO binding and the essential role of MPc units in tuning and amplifying the sensing response.

Indexed as

Biosensing TechniquesElectrochemical TechniquesCarbon MonoxideCopperMetal-Organic FrameworksParticle SizeCarbon MonoxideCopperMetal-Organic Frameworkscarbon monoxidechemiresistorsconductivemetallophthalocyaninestwo-dimensional

Identifiers

PMID34796599
PMCPMC8797516
OpenAlexW3212283827

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.