ArticleAngewandte Chemie (International ed. in English)2022
Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular-Level Insights into the Electrical Double Layer.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
What it found
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Who cites it
12 citing papers in PubMed.
- Nanomaterials Electrochemistry: Insights for Materials Scientists and Electrochemists.ACS nano · 2026Article
- Grand Challenges and Opportunities in Stimulated Dynamic and Resonant Catalysis.ACS catalysis · 2026Review
- Quantum-Scale Friction at Solid-Liquid Interface: Simulation, Detection Techniques, Mechanisms, and Emerging Applications.Nano-micro letters · 2026Review
- Capacitive photocharging of gold nanorods.Nature communications · 2025Article
- Stochastic Impact Electrochemistry of Alkanethiolate-Functionalized Silver Nanoparticles.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Revealing the molecular interplay of coverage, wettability, and capacitive response at the Pt(111)-water solution interface under bias.Communications chemistry · 2025Article
- Electronic Response and Charge Inversion at Polarized Gold Electrode.Angewandte Chemie (International ed. in English) · 2025Article
- The role of the water contact layer on hydration and transport at solid/liquid interfaces.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Single-Nanoparticle Electrochemical Collision for Monitoring Self-Assembly of Thiol Molecules on Au Nanoparticles.Biosensors · 2024Article
- Tuning Acid-Base Chemistry at an Electrified Gold/Water Interface.Journal of the American Chemical Society · 2024Article
- Probing the Gold/Water Interface with Surface-Specific Spectroscopy.ACS physical chemistry Au · 2023Article
- Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular-Level Insights into the Electrical Double Layer.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
The electrical double-layer plays a key role in important interfacial electrochemical processes from catalysis to energy storage and corrosion. Therefore, understanding its structure is crucial for the progress of sustainable technologies. We extract new physico-chemical information on the capacitance and structure of the electrical double-layer of platinum and gold nanoparticles at the molecular level, employing single nanoparticle electrochemistry. The charge storage ability of the solid/liquid interface is larger by one order-of-magnitude than predicted by the traditional mean-field models of the double-layer such as the Gouy-Chapman-Stern model. Performing molecular dynamics simulations, we investigate the possible relationship between the measured high capacitance and adsorption strength of the water adlayer formed at the metal surface. These insights may launch the active tuning of solid-solvent and solvent-solvent interactions as an innovative design strategy to transform energy technologies towards superior performance and sustainability.
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Registered trials
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