Evidence map›Paper›PMID 34795221›Full record

ArticleNature communications2021

Dynamic transformation of cubic copper catalysts during CO

Philipp Grosse, Aram Yoon, Clara Rettenmaier, Antonia Herzog, See Wee Chee, Beatriz Roldan Cuenya

Erratum issuedOpen access · goldAbstract read
In one paragraph

Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 61 papers.

0numbers the graph read from it
0cells of the map it votes in
61citing papers in PubMed
7.3field-weighted citation impact, top 2% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

61 citing papers in PubMed, 235 citations in OpenAlex.

  1. Review
  2. CuSmall (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  3. Review
  4. Article
  5. Chemical and Morphological Changes of Chloride-Affected Cu Catalysts during COThe journal of physical chemistry. C, Nanomaterials and interfaces · 2026
    Article
  6. Article
  7. Article
  8. Article
  9. Highly Selective Electrochemical Bicarbonate Conversion across CJournal of the American Chemical Society · 2026
    Article
  10. Article
  11. Oxides and Carbonates Accelerate Copper Instability in COJournal of the American Chemical Society · 2026
    Article
  12. Article
  13. OJournal of the American Chemical Society · 2026
    Article
  14. Article
  15. Article
  16. Article
  17. Article
  18. Article
  19. Article
  20. Article

1 more citing papers are in PubMed but not listed here.

4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

6 authors at 1 institution in 1 country.

Philipp Grosse *Department of Interface Science, Fritz-Haber Institute of the Max Planck Society, 14195, Berlin, Germany.
Aram Yoon *Department of Interface Science, Fritz-Haber Institute of the Max Planck Society, 14195, Berlin, Germany.
Clara RettenmaierDepartment of Interface Science, Fritz-Haber Institute of the Max Planck Society, 14195, Berlin, Germany.
Antonia HerzogDepartment of Interface Science, Fritz-Haber Institute of the Max Planck Society, 14195, Berlin, Germany.
See Wee CheeDepartment of Interface Science, Fritz-Haber Institute of the Max Planck Society, 14195, Berlin, Germany. swchee@fhi-berlin.mpg.de.ORCID http://orcid.org/0000-0003-0095-3242
Beatriz Roldan CuenyaDepartment of Interface Science, Fritz-Haber Institute of the Max Planck Society, 14195, Berlin, Germany. roldan@fhi-berlin.mpg.de.ORCID http://orcid.org/0000-0002-8025-307X
Fritz Haber Institute of the Max Planck Society · DE

Funding

Deutsche Forschungsgemeinschaft (German Research Foundation) SPP 2080-406944504, CRC 1316 subproject B1EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council) ERC-725915
6 · The paper itself

Abstract

To rationally design effective and stable catalysts for energy conversion applications, we need to understand how they transform under reaction conditions and reveal their underlying structure-property relationships. This is especially important for catalysts used in the electroreduction of carbon dioxide where product selectivity is sensitive to catalyst structure. Here, we present real-time electrochemical liquid cell transmission electron microscopy studies showing the restructuring of copper(I) oxide cubes during reaction. Fragmentation of the solid cubes, re-deposition of new nanoparticles, catalyst detachment and catalyst aggregation are observed as a function of the applied potential and time. Using cubes with different initial sizes and loading, we further correlate this dynamic morphology with the catalytic selectivity through time-resolved scanning electron microscopy measurements and product analysis. These comparative studies reveal the impact of nanoparticle re-deposition and detachment on the catalyst reactivity, and how the increased surface metal loading created by re-deposited nanoparticles can lead to enhanced C

Identifiers

PMID34795221
PMCPMC8602378
OpenAlexW3211248210

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.