Evidence map›Paper›PMID 34793128›Full record

ReviewChemical reviews2022

Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis.

Amy Y Chan, Ian B Perry, Noah B Bissonnette, Benito F Buksh, Grant A Edwards, Lucas I Frye, Olivia L Garry, Marissa N Lavagnino, Beryl X Li, Yufan Liang and 7 more

Abstract readReview
In one paragraph

Review in Chemical reviews, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 355 papers.

0numbers the graph read from it
0cells of the map it votes in
355citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

355 citing papers in PubMed.

  1. Article
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  13. Regio-, Stereo-, and Enantioselective C(spAngewandte Chemie (International ed. in English) · 2026
    Article
  14. Review
  15. Review
  16. Enantioselective Vinyl Radical Addition to Aldehydes via Dual Chromium Catalysis.Angewandte Chemie (International ed. in English) · 2026
    Article
  17. Article
  18. Review
  19. Review
  20. Article

295 more citing papers are in PubMed but not listed here.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

17 authors.

Amy Y ChanMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
Ian B PerryMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
Noah B BissonnetteMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.ORCID 0000-0001-6892-5040
Benito F BukshMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
Grant A EdwardsMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
Lucas I FryeMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.ORCID 0000-0001-7713-7097
Olivia L GarryMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
Marissa N LavagninoMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.ORCID 0000-0001-6851-919X
Beryl X LiMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
Yufan LiangMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
Edna MaoMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
Agustin MilletMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
James V OakleyMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
Nicholas L ReedMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.ORCID 0000-0003-4234-5464
Holt A SakaiMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
Ciaran P SeathMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.
David W C MacMillanMerck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States.ORCID 0000-0001-6447-0587

Funding

Photoredox Catalysis Applications in Organometallics and Chemical BiologyR35GM134897 · NIGMS · PRINCETON UNIVERSITY · PI David W MacMillan · 2020 to 2026
$6.3M
NIGMS NIH HHS R35 GM134897
6 · The paper itself

Abstract

The merger of photoredox catalysis with transition metal catalysis, termed metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past decade. Metallaphotoredox catalysis has combined the unparalleled capacity of transition metal catalysis for bond formation with the broad utility of photoinduced electron- and energy-transfer processes. Photocatalytic substrate activation has allowed the engagement of simple starting materials in metal-mediated bond-forming processes. Moreover, electron or energy transfer directly with key organometallic intermediates has provided novel activation modes entirely complementary to traditional catalytic platforms. This Review details and contextualizes the advancements in molecule construction brought forth by metallaphotocatalysis.

Indexed as

ElectronsTransition ElementsCatalysisNickelOxidation-ReductionNickelTransition Elements

Identifiers

PMID34793128
PMCPMC12232520

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.