Evidence map›Paper›PMID 34787414›Full record

ArticleInorganic chemistry2021

Extensive Redox Non-Innocence in Iron Bipyridine-Diimine Complexes: a Combined Spectroscopic and Computational Study.

Ranjeesh Thenarukandiyil, Eno Paenurk, Anthony Wong, Natalia Fridman, Amir Karton, Raanan Carmieli, Gabriel Ménard, Renana Gershoni-Poranne, Graham de Ruiter

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In one paragraph

Article in Inorganic chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Ranjeesh ThenarukandiyilSchulich Faculty of Chemistry, Technion - Israel Institute of Technology, Technion City, 3200008 Haifa, Israel.
Eno PaenurkLaboratorium für Organische Chemie, ETH Zurich, Vladimir-Prelog-Weg 2, Zurich 8093, Switzerland.ORCID https://orcid.org/0000-0002-6921-757X
Anthony WongDepartment of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, United States.ORCID https://orcid.org/0000-0001-6918-2437
Natalia FridmanSchulich Faculty of Chemistry, Technion - Israel Institute of Technology, Technion City, 3200008 Haifa, Israel.
Amir KartonSchool of Molecular Science, The University of Western Australia, 35 Stirling Highway, 6009 Perth, Australia.ORCID https://orcid.org/0000-0002-7981-508X
Raanan CarmieliDepartment of Chemical Research Support, Weizmann Institute of Science, Rehovot 761000, Israel.ORCID https://orcid.org/0000-0003-4418-916X
Gabriel MénardDepartment of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, United States.ORCID https://orcid.org/0000-0002-2801-0863
Renana Gershoni-PoranneSchulich Faculty of Chemistry, Technion - Israel Institute of Technology, Technion City, 3200008 Haifa, Israel.ORCID https://orcid.org/0000-0002-2233-6854
Graham de RuiterSchulich Faculty of Chemistry, Technion - Israel Institute of Technology, Technion City, 3200008 Haifa, Israel.ORCID https://orcid.org/0000-0001-6008-286X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Metal-ligand cooperation is an important aspect in earth-abundant metal catalysis. Utilizing ligands as electron reservoirs to supplement the redox chemistry of the metal has resulted in many new exciting discoveries. Here, we demonstrate that iron bipyridine-diimine (BDI) complexes exhibit an extensive electron-transfer series that spans a total of five oxidation states, ranging from the trication [Fe(BDI)]

Identifiers

PMID34787414
PMCPMC8653161

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.