ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
From Thioureas to Thioquinolines through Isolated Benzothiazines by Gold Catalysis.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Gold-Catalyzed 1,3-Thiazine Formation and Uncommon Tautomer Isolation.The Journal of organic chemistry · 2022Article
- From Thioureas to Thioquinolines through Isolated Benzothiazines by Gold Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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2 authors.
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Abstract
New benzothiazine heterocycles have been formed from thiourea derivatives by using different gold catalysts. The catalyst and the conditions were optimised towards the selective synthesis of six-membered benzothiazine heterocycles, characterised by X-ray diffraction. Interestingly, these organic compounds evolved under gold catalysis in basic medium to achieve the formation of amino thioquinolines through an unprecedented aromatisation process of the heterocycle. The reaction was also carried out stoichiometrically by reaction with gold complexes to afford thioquinolines coordinated to the gold fragment. Benzothiazine, amino thioquinoline heterocycles and gold-derived species have a great potential for biological applications.
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