Evidence map›Paper›PMID 34782461›Full record

ArticleProceedings of the National Academy of Sciences of the United States of America2021

Stripping away ion hydration shells in electrical double-layer formation: Water networks matter.

Serena R Alfarano, Simone Pezzotti, Christopher J Stein, Zhou Lin, Federico Sebastiani, Sarah Funke, Claudius Hoberg, Inga Kolling, Chun Yu Ma, Katja Mauelshagen and 9 more

Open access · hybridAbstract read
In one paragraph

Article in Proceedings of the National Academy of Sciences of the United States of America, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.

0numbers the graph read from it
0cells of the map it votes in
19citing papers in PubMed
5.9field-weighted citation impact, top 3% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

19 citing papers in PubMed, 65 citations in OpenAlex.

  1. Editable Hydrogen Bond Network Within the Electric Double Layer for COAngewandte Chemie (International ed. in English) · 2026
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  12. Electronic Response and Charge Inversion at Polarized Gold Electrode.Angewandte Chemie (International ed. in English) · 2025
    Article
  13. Article
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  16. Tuning Acid-Base Chemistry at an Electrified Gold/Water Interface.Journal of the American Chemical Society · 2024
    Article
  17. Impedance of nanocapacitors from molecular simulations to understand the dynamics of confined electrolytes.Proceedings of the National Academy of Sciences of the United States of America · 2024
    Article
  18. Article
  19. Nature of the Electrical Double Layer on Suspended Graphene Electrodes.Journal of the American Chemical Society · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

19 authors at 6 institutions in 3 countries.

Serena R AlfaranoLehrstuhl für Physikalische Chemie II, Ruhr-Universität Bochum 44780 Bochum, Germany.
Simone PezzottiLehrstuhl für Physikalische Chemie II, Ruhr-Universität Bochum 44780 Bochum, Germany.
Christopher J SteinDepartment of Chemistry, University of California, Berkeley, CA 94720.
Zhou LinDepartment of Chemistry, University of California, Berkeley, CA 94720.ORCID 0000-0003-3271-5345
Federico SebastianiLehrstuhl für Physikalische Chemie II, Ruhr-Universität Bochum 44780 Bochum, Germany.
Sarah FunkeLehrstuhl für Physikalische Chemie II, Ruhr-Universität Bochum 44780 Bochum, Germany.ORCID 0000-0003-1405-5005
Claudius HobergLehrstuhl für Physikalische Chemie II, Ruhr-Universität Bochum 44780 Bochum, Germany.
Inga KollingLehrstuhl für Physikalische Chemie II, Ruhr-Universität Bochum 44780 Bochum, Germany.
Chun Yu MaLehrstuhl für Physikalische Chemie II, Ruhr-Universität Bochum 44780 Bochum, Germany.
Katja MauelshagenLehrstuhl für Physikalische Chemie II, Ruhr-Universität Bochum 44780 Bochum, Germany.
Thorsten OckelmannLehrstuhl für Physikalische Chemie II, Ruhr-Universität Bochum 44780 Bochum, Germany.
Gerhard SchwaabLehrstuhl für Physikalische Chemie II, Ruhr-Universität Bochum 44780 Bochum, Germany.ORCID 0000-0003-2136-907X
Li FuUniversité de Lyon, Université Claude Bernard Lyon 1, CNRS, Institut Lumière Matière F-69622 Villeurbanne, France.ORCID 0000-0001-5979-6590
Jean-Blaise BrubachSynchrotron Soleil, AILES beamline, L'Orme des Merisiers 91192 Gif sur Yvette Cedex, France.
Pascale RoySynchrotron Soleil, AILES beamline, L'Orme des Merisiers 91192 Gif sur Yvette Cedex, France.
Martin Head-GordonDepartment of Chemistry, University of California, Berkeley, CA 94720; mhg@cchem.berkeley.edu kristina.tschulik@rub.de mgaigeot@univ-evry.fr martina.havenith@rub.de.ORCID 0000-0002-4309-6669
Kristina TschulikFaculty of Chemistry and Biochemistry, Chair of Analytical Chemistry II, Ruhr University Bochum 44780 Bochum, Germany mhg@cchem.berkeley.edu kristina.tschulik@rub.de mgaigeot@univ-evry.fr martina.havenith@rub.de.
Marie-Pierre GaigeotUniversité Paris-Saclay, Univ Evry, CNRS, LAMBE UMR8586, Evry-Courcouronnes 91025, France; mhg@cchem.berkeley.edu kristina.tschulik@rub.de mgaigeot@univ-evry.fr martina.havenith@rub.de.
Martina HavenithLehrstuhl für Physikalische Chemie II, Ruhr-Universität Bochum 44780 Bochum, Germany; mhg@cchem.berkeley.edu kristina.tschulik@rub.de mgaigeot@univ-evry.fr martina.havenith@rub.de.ORCID 0000-0001-8475-5037
Ruhr University Bochum · DECentre National de la Recherche Scientifique · FRLawrence Berkeley National Laboratory · USSynchrotron soleil · FRUniversité Claude Bernard Lyon 1 · FRUniversity of Duisburg-Essen · DE

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The double layer at the solid/electrolyte interface is a key concept in electrochemistry. Here, we present an experimental study combined with simulations, which provides a molecular picture of the double-layer formation under applied voltage. By THz spectroscopy we are able to follow the stripping away of the cation/anion hydration shells for an NaCl electrolyte at the Au surface when decreasing/increasing the bias potential. While Na

Indexed as

double layerelectrochemistryelectrolytehydrogen bondingoperando

Identifiers

PMID34782461
PMCPMC8617503
OpenAlexW3214534703

What OpenQuestion holds

Textmetadata
LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.