ArticleChemical science2021
Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks.
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Lithium Ion-Conducting Triazacoronene-Based Neutral 2D Covalent Organic Framework as a Solid-State Electrolyte.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Metal-Organic Framework-Based Supercapacitors: A Comprehensive Review.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Homometallic Intervalence Charge Transfer Band of Co(II/III) Induced by Phase Transitions in a Heterometallic Co-W Charge Transfer Photomagnet.Small science · 2026Article
- The Ratio of spAngewandte Chemie (International ed. in English) · 2025Article
- Mixed Ionic and Electronic Conductivity in a Tetrathiafulvalene-Phosphonate Metal-Organic Framework.Journal of the American Chemical Society · 2025Article
- Redox-Active Metal-Organic Frameworks with Three-Dimensional Lattice Containing theMolecules (Basel, Switzerland) · 2022Article
- An electrically conductive metallocycle: densely packed molecular hexagons with π-stacked radicals.Chemical science · 2022Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Achieving a molecular-level understanding of how the structures and compositions of metal-organic frameworks (MOFs) influence their charge carrier concentration and charge transport mechanism-the two key parameters of electrical conductivity-is essential for the successful development of electrically conducting MOFs, which have recently emerged as one of the most coveted functional materials due to their diverse potential applications in advanced electronics and energy technologies. Herein, we have constructed four new alkali metal (Na, K, Rb, and Cs) frameworks based on an electron-rich tetrathiafulvalene tetracarboxylate (TTFTC) ligand, which formed continuous π-stacks, albeit with different π-π-stacking and S⋯S distances (
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Registered trials
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