Evidence map›Paper›PMID 34771235›Full record

ArticlePolymers2021

Structure of Polytetrafluoroethylene Modified by the Combined Action of γ-Radiation and High Temperatures.

Alexander Sergeevich Smolyanskii, Ekaterina Dmitrievna Politova, Ol'ga Alekseevna Koshkina, Mikhail Aleksandrovich Arsentyev, Pavel Prokof'evich Kusch, Lev Vladimirovich Moskvitin, Sergei Vital'evich Slesarenko, Dmitrii Pavlovich Kiryukhin, Leonid Izrailevich Trakhtenberg

Abstract read
In one paragraph

Article in Polymers, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Alexander Sergeevich SmolyanskiiHigh Energy Chemistry and Radioecology Department, D. Mendeleev University of Chemical Technology of Russia, Miusskaya Ploshchad 125047, Moscow, Russia.ORCID 0000-0003-2932-2225
Ekaterina Dmitrievna PolitovaLaboratory of Functional Nanocomposites, N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Science, Moscow 119991, Moscow, Russia.ORCID 0000-0002-4158-6314
Ol'ga Alekseevna KoshkinaLaboratory of Functional Nanocomposites, N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Science, Moscow 119991, Moscow, Russia.
Mikhail Aleksandrovich ArsentyevTechnology Department, Quantum R LLC, Skolkovo 125319, Moscow, Russia.
Pavel Prokof'evich KuschLaboratory of Cryochemistry and Radiation Chemistry, The Institute of Problems of Chemical Physics, Russian Academy of Science, Chernogolovka 142400, Moscow, Russia.
Lev Vladimirovich MoskvitinHigh Energy Chemistry and Radioecology Department, D. Mendeleev University of Chemical Technology of Russia, Miusskaya Ploshchad 125047, Moscow, Russia.ORCID 0000-0002-8642-5223
Sergei Vital'evich SlesarenkoTechnology Department, Quantum R LLC, Skolkovo 125319, Moscow, Russia.
Dmitrii Pavlovich KiryukhinLaboratory of Cryochemistry and Radiation Chemistry, The Institute of Problems of Chemical Physics, Russian Academy of Science, Chernogolovka 142400, Moscow, Russia.
Leonid Izrailevich TrakhtenbergLaboratory of Functional Nanocomposites, N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Science, Moscow 119991, Moscow, Russia.

Funding

Ministry of Higher Education and Science of the Russian Federation AAAA-A19-119041090087-4Ministry of Higher Education and Science of the Russian Federation State assignment No. 45.22, registration number AAAA-A18-118012390045-2
6 · The paper itself

Abstract

By means of X-ray computed microtomography (XCMT), the existence of a developed porous structure with an average pore diameter of ~3.5 μm and pore content of ~1.1 vol.% has been revealed in unirradiated polytetrafluoroethylene (PTFE). It has been found that the combined action of gamma radiation (absorbed dose per PTFE of ~170 kGy) and high temperatures (327-350 °C) leads to the disappearance of the porous structure and the formation of several large pores with sizes from 30 to 50 μm in the bulk of thermal-radiation modified PTFE (TRM-PTFE). It has been established by X-ray diffraction (XRD) analysis that the thermal-radiation modification of PTFE leads to an increase in the interplanar spacings, the degree of crystallinity and the volume of the unit cell, as well as to a decrease in the size of crystals and the X-ray density of the crystalline phase in comparison with the initial polymer. It is assumed that the previously-established effect of improving the deformation-strength and tribological properties of the TRM-PTFE can be due not only to the radiation cross-linking of polymer chains but also to the disappearance of the pore system and to the ordering of the crystalline phase of PTFE.

Indexed as

cross-linkingcrystallizationhigh temperaturesionizing radiationmodificationpolytetrafluoroethyleneporestructure

Identifiers

PMID34771235
PMCPMC8587590

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.