ArticleChemical science2021
Enantioselective palladaelectro-catalyzed C-H olefinations and allylations for N-C axial chirality.
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Unlocking the Alkynyl Bromide Radical Anion With Alternating Current for Inverse Sonogashira C─H Coupling.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Access to C─N and N─N Axially Chiral Pyridinones via NHC-Catalyzed Dynamic Kinetic Resolution of Rotationally Restricted Cyclic Imides.Angewandte Chemie (International ed. in English) · 2026Article
- A unified cobalt-electrocatalytic platform for enantio- and stereo-selective C-H and C-F functionalization ofChemical science · 2026Article
- Recent Advances in the Synthesis of C-N/N-N Atropisomers via Asymmetric Annulation.Topics in current chemistry (Cham) · 2026Review
- Parametrization of κACS catalysis · 2025Article
- Atroposelective catalysis.Nature reviews. Chemistry · 2024Review
- Iron-catalyzed stereoselective C-H alkylation for simultaneous construction of C-N axial and C-central chirality.Nature communications · 2024Article
- The crucial role of silver(I)-salts as additives in C-H activation reactions: overall analysis of their versatility and applicability.Chemical Society reviews · 2023Review
- Cobaltaelectro-Catalyzed C-H Annulation with Allenes for Atropochiral andACS catalysis · 2023Article
- Cobalt-catalyzed enantioselective intramolecular reductive cyclization via electrochemistry.Nature communications · 2023Article
- Silver-Free C-H Activation: Strategic Approaches towards Realizing the Full Potential of C-H Activation in Sustainable Organic Synthesis.Angewandte Chemie (International ed. in English) · 2022Review
- Ruthenium(II)/Imidazolidine Carboxylic Acid-Catalyzed C-H Alkylation for Central and Axial Double Enantio-Induction.Angewandte Chemie (International ed. in English) · 2022Article
- Palladium-catalyzed asymmetric allylic 4-pyridinylation via electroreductive substitution reaction.Nature communications · 2022Article
- PdAngewandte Chemie (International ed. in English) · 2022Article
- Asymmetric Synthesis of Axially Chiral C-N Atropisomers.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Review
- Thioether-enabled palladium-catalyzed atroposelective C-H olefination for N-C and C-C axial chirality.Chemical science · 2022Article
- Atropoenantioselective palladaelectro-catalyzed anilide C-H olefinations viable with natural sunlight as sustainable power source.Chemical science · 2022Article
- Electrooxidative palladium- and enantioselective rhodium-catalyzed [3 + 2] spiroannulations.Chemical science · 2022Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Enantioselective palladaelectro-catalyzed C-H alkenylations and allylations were achieved with easily-accessible amino acids as transient directing groups. This strategy provided access to highly enantiomerically-enriched N-C axially chiral scaffolds under exceedingly mild conditions. The synthetic utility of our strategy was demonstrated by a variety of alkenes, while the versatility of our approach was reflected by atroposelective C-H allylations. Computational studies provided insights into a facile C-H activation by a seven-membered palladacycle.
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