ArticleChemical science2021
Cooperative C-H activation of pyridine by PBP complexes of Rh and Ir can lead to bridging 2-pyridyls with different connectivity to the B-M unit.
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 19 citations in OpenAlex.
- Alkyne insertion at a nickel-aluminum heterometallic complex: implications for pyridine alkenylation.Chemical science · 2026Article
- Flash Communication: A Metal-First Approach to Ruthenium Complexes of a Boryl-Centered POBOP Pincer Ligand.Organometallics · 2026Article
- C(spAngewandte Chemie (International ed. in English) · 2025Article
- Impact of Halide (Cl vs I) Identity on the Preferred Positioning of Substituents between Al and M (M = Co, Rh, Ir) in PAlP Pincer Complexes.Organometallics · 2025Article
- Iridium Complexes of a Bis(Inorganic chemistry · 2024Article
- C-H Activation of Pyridines by Boryl Pincer Complexes: Elucidation of Boryl-Directed C-H Oxidative Addition to Ir and Discovery of Transition Metal-Assisted Reductive Elimination from Boron at Rh.Journal of the American Chemical Society · 2024Article
- Cooperative activation of carbon-hydrogen bonds by heterobimetallic systems.Dalton transactions (Cambridge, England : 2003) · 2024Review
- Migration of Hydride, Methyl, and Chloride Ligands between Al and M in (PAlP)M Pincer Complexes (M = Rh or Ir).Organometallics · 2023Article
- Rhodium-Promoted C-H Bond Activation of Quinoline, Methylquinolines, and Related Mono-Substituted Quinolines.Organometallics · 2022Article
- Cooperative C-H Bond Activation by a Low-Spin dJournal of the American Chemical Society · 2022Article
Corrections and comments
- Erratum issued
Authors and funding
5 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Pyridine and quinoline undergo selective C-H activation in the 2-position with Rh and Ir complexes of a boryl/bis(phosphine) PBP pincer ligand, resulting in a 2-pyridyl bridging the transition metal and the boron center. Examination of this reactivity with Rh and Ir complexes carrying different non-pincer ligands on the transition metal led to the realization of the possible isomerism derived from the 2-pyridyl fragment connecting either
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Registered trials
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