Evidence map›Paper›PMID 34745531›Full record

ArticleChemical science2021

Temperature-dependent modulation by biaryl-based monomers of the chain length and morphology of biphenyl-based supramolecular polymers.

Tomokazu Iseki, Mathijs F J Mabesoone, Mark A J Koenis, Brigitte A G Lamers, Elisabeth Weyandt, Lafayette N J de Windt, Wybren Jan Buma, Anja R A Palmans, E W Meijer

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Tomokazu IsekiInstitute for Complex Molecular Systems and Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology 5600 MB Eindhoven The Netherlands e.w.meijer@tue.nl.ORCID https://orcid.org/0000-0002-2927-7033
Mathijs F J MabesooneInstitute for Complex Molecular Systems and Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology 5600 MB Eindhoven The Netherlands e.w.meijer@tue.nl.
Mark A J KoenisVan't Hoff Institute for Molecular Sciences, University of Amsterdam Science Park 904 1098 XH Amsterdam The Netherlands.ORCID https://orcid.org/0000-0002-4589-1965
Brigitte A G LamersInstitute for Complex Molecular Systems and Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology 5600 MB Eindhoven The Netherlands e.w.meijer@tue.nl.ORCID https://orcid.org/0000-0002-3312-8962
Elisabeth WeyandtInstitute for Complex Molecular Systems and Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology 5600 MB Eindhoven The Netherlands e.w.meijer@tue.nl.ORCID https://orcid.org/0000-0002-6024-9145
Lafayette N J de WindtInstitute for Complex Molecular Systems and Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology 5600 MB Eindhoven The Netherlands e.w.meijer@tue.nl.
Wybren Jan BumaVan't Hoff Institute for Molecular Sciences, University of Amsterdam Science Park 904 1098 XH Amsterdam The Netherlands.ORCID https://orcid.org/0000-0002-1265-8016
Anja R A PalmansInstitute for Complex Molecular Systems and Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology 5600 MB Eindhoven The Netherlands e.w.meijer@tue.nl.ORCID https://orcid.org/0000-0002-7201-1548
E W MeijerInstitute for Complex Molecular Systems and Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology 5600 MB Eindhoven The Netherlands e.w.meijer@tue.nl.ORCID https://orcid.org/0000-0003-4126-7492

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Supramolecular copolymerizations offer attractive options to introduce structural and functional diversity in supramolecular polymer materials. Yet, general principles and structure-property relationships for rational comonomer design remain lacking. Here, we report on the supramolecular (co)aggregation of a phenylpyridine and bipyridine derivative of a recently reported biphenyl tetracarboxamide-based monomer. We show that both arylpyridines are poor monomers for supramolecular homopolymerizations. However, the two arylpyridines efficiently influence supramolecular polymers of a biphenyl-based polymer. The phenylpyridine derivatives primarily sequestrate biphenyl monomers, while the bipyridine intercalates into the polymers at high temperatures. Thereby, these two poorly homopolymerizing monomers allow for a fine control over the length of the biphenyl-based supramolecular polymers. As such, our results highlight the potential to control the structure and morphology of supramolecular polymers by tailoring the electronic properties of additives.

Identifiers

PMID34745531
PMCPMC8513997

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.