ArticleAngewandte Chemie (International ed. in English)2022
A Selective and General Cobalt-Catalyzed Hydroaminomethylation of Olefins to Amines.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 33 citations in OpenAlex.
- Heterogeneous hydroformylation of propene over surface rhodium coordinated by immobilized multi-N ligands.Science advances · 2026Article
- Cobalt-catalyzed synthesis of amides from alkenes and amines promoted by light.Science (New York, N.Y.) · 2024Article
- An Intramolecular Hydroaminomethylation-Based Approach to Pyrrolizidine Alkaloids under Microwave-Assisted Heating.Molecules (Basel, Switzerland) · 2022Article
- Leveraging Electron-Deficient Iminium Intermediates in a General Synthesis of Valuable Amines.Angewandte Chemie (International ed. in English) · 2022Article
- Nutzung von elektronenarmen Iminiumintermediaten zur Synthese von wertvollen Aminen.Angewandte Chemie (Weinheim an der Bergstrasse, Germany) · 2022Article
- A Selective and General Cobalt-Catalyzed Hydroaminomethylation of Olefins to Amines.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A new cobalt catalyst is presented for the domino hydroformylation-reductive amination reaction of olefins. The optimal Co-tert-BuPy-Xantphos catalyst shows good to excellent linear-to-branched (n/iso) regioselectivity for the reactions of aliphatic alkenes with aromatic amines under mild conditions. This system is far more selective than traditional cobalt(I) catalysts and even better than most known rhodium catalysts.
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Registered trials
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