ArticleAngewandte Chemie (International ed. in English)2021
Room-Temperature Spin-Dependent Transport in Metalloporphyrin-Based Supramolecular Wires.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Room Temperature Spin-Dependent Transport in 2D Hofmann-Type Single-Layer Network.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Dipole-Induced Inversion of Spin-Dependent Charge Transport through α-Helical Peptide-Based Single-Molecule Junctions.Journal of the American Chemical Society · 2025Article
- Effects of Electrode Materials on Electron Transport for Single-Molecule Junctions.International journal of molecular sciences · 2023Review
- Room-Temperature Spin-Dependent Transport in Metalloporphyrin-Based Supramolecular Wires.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
10 authors.
Funding
Abstract
Here we present room-temperature spin-dependent charge transport measurements in single-molecule junctions made of metalloporphyrin-based supramolecular assemblies. They display large conductance switching for magnetoresistance in a single-molecule junction. The magnetoresistance depends acutely on the probed electron pathway through the supramolecular wire: those involving the metal center showed marked magnetoresistance effects as opposed to those exclusively involving the porphyrin ring which present nearly complete absence of spin-dependent charge transport. The molecular junction magnetoresistance is highly anisotropic, being observable when the magnetization of the ferromagnetic junction electrode is oriented along the main molecular junction axis, and almost suppressed when it is perpendicular. The key ingredients for the above effect to manifest are the electronic structure of the paramagnetic metalloporphyrin, and the spinterface created at the molecule-electrode contact.
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