Investigation of catalytic effect on carbon-carbon bond formation by Baylis-Hillman (BH) reaction between (2/3/4)-nitro-arylaldehyde and alkylacrylates and computational approaches through DFT functional.

Laila Arifun Nahar, Ajoy Kumer, Md Wahab Khan

Open access · goldAbstract read

In one paragraph

Article in Heliyon, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

0.2field-weighted citation impact, top 51% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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3 · Its place in the literature

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0 citing papers in PubMed, 2 citations in OpenAlex.

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4 · The record

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5 · Who and what money

Authors and funding

3 authors at 1 institution in 1 country.

Laila Arifun NaharOrganic Research Laboratory, Department of Chemistry, Bangladesh University of Engineering and Technology (BUET), Dhaka, 1000, Bangladesh.

Ajoy KumerOrganic Research Laboratory, Department of Chemistry, Bangladesh University of Engineering and Technology (BUET), Dhaka, 1000, Bangladesh.

Md Wahab KhanOrganic Research Laboratory, Department of Chemistry, Bangladesh University of Engineering and Technology (BUET), Dhaka, 1000, Bangladesh.

Bangladesh University of Engineering and Technology · BD

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The 4-diazabicyclo[2. 2. 2] octane, DABCO, had widely established with gigantic and celestial applications on catalysis for carbon-carbon bond formation reactions. Thus, it has been employed to synthesize the alkyl 2-(hydroxyl (nitrophenyl) methyl)acrylate by the reaction of arylaldehydes and alkylacrylates under a mild condition with good yields. First of all, reaction was examined effect of various solvents, such as water, MeOH, Dioxane, DMSO, t-Butanol, DMF, Toluene, and THF and THF was the best solvent in term of yield. Next, the room temperature (R.T) was the optimized condition than 60 °C and 80 °C. The overall reaction progress was monitored in presence of DABCO, Et

Indexed as

AlkylacrylatesArylaldehydeCarbon-carbon bond and DFTComputational chemistryDABCO

Identifiers

PMID34712852

DOI10.1016/j.heliyon.2021.e08139

PMCPMC8529513

OpenAlexW3205099066

What OpenQuestion holds

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LicenceCC BY

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.