Cr release after Cr(III) and Cr(VI) enrichment from different layers of cast iron corrosion scales in drinking water distribution systems: the impact of pH, temperature, sulfate, and chloride.

Chromium accumulated from source water and pipeline lining materials in corrosion scales could potentially be released into bulk water in drinking water distribution systems (DWDS). This study examined the influence of pH (pH 4, pH 5.5, pH 7, pH 8.5, pH 10), temperature (5 °C, 15 °C, 25 °C), sulfate (50 mg/L, 150 mg/L, 250 mg/L), and chloride (50 mg/L, 150 mg/L, 250 mg/L) on chromium accumulation and release between iron corrosion scale phase and the surrounding water phase. For the first time, the accumulation and release behaviors of chromium were assessed and compared in two distinct layers of iron corrosion scales based on the speciation distributions of heavy metals. Results showed that in the outer and inner layers of corrosion scales, chromium exhibited an almost similar trend but significant differences in quantity, with the outer layer accumulating less and releasing more. In particular, the average difference of chromium released after Cr(VI) enrichment from the outer and inner layers was 50.53 μg/L under the same conditions. Further studies conclusively showed that in Cr(VI) accumulation process, a portion of Cr(VI) would be reduced to Cr(III) by Fe(II) in iron corrosion scales. The mechanisms of chromium retention based on different iron (oxyhydr)oxides were discussed.