Evidence map›Paper›PMID 34698493›Full record

ArticleJournal of the American Chemical Society2021

Direct Aerobic Generation of a Ferric Hydroperoxo Intermediate Via a Preorganized Secondary Coordination Sphere.

Kate A Jesse, Sophie W Anferov, Kelsey A Collins, Juan A Valdez-Moreira, Maia E Czaikowski, Alexander S Filatov, John S Anderson

Open access · hybridAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
0.9field-weighted citation impact, top 27% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 15 citations in OpenAlex.

  1. Mechanism of Lutein tobioRxiv : the preprint server for biology · 2025
    Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. A cobalt adduct of an N-hydroxy-piperidinium cation.Journal of coordination chemistry · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 3 institutions in 1 country.

Kate A JesseDepartment of Chemistry, The University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0002-3527-4007
Sophie W AnferovDepartment of Chemistry, The University of Chicago, Chicago, Illinois 60637, United States.
Kelsey A CollinsDepartment of Chemistry, Northwestern University, Evanston, Illinois 60208, United States.
Juan A Valdez-MoreiraDepartment of Chemistry, Indiana University, Bloomington, Indiana 47405, United States.
Maia E CzaikowskiDepartment of Chemistry, The University of Chicago, Chicago, Illinois 60637, United States.
Alexander S FilatovDepartment of Chemistry, The University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0002-8378-1994
John S AndersonDepartment of Chemistry, The University of Chicago, Chicago, Illinois 60637, United States.ORCID 0000-0002-0730-3018
University of Chicago · USIndiana University Bloomington · USNorthwestern University · US

Funding

Equipment Supplement: Distal Anion Stabilization of Biologically Relevant Oxo IntermediatesR35GM133470 · NIGMS · UNIVERSITY OF CHICAGO · PI ANDERSON, JOHN STUART · 2019 to 2023
$2.1M
NIGMS NIH HHS R35 GM133470
6 · The paper itself

Abstract

Enzymes exert control over the reactivity of metal centers with precise tuning of the secondary coordination sphere of active sites. One particularly elegant illustration of this principle is in the controlled delivery of proton and electron equivalents in order to activate abundant but kinetically inert oxidants such as O

Indexed as

Coordination ComplexesHydrazonesIronLigandsOxidation-ReductionOxygenPeroxidesPyrrolesCoordination ComplexesHydrazonesIronLigandsOxygenPeroxidesPyrroles

Identifiers

PMID34698493
PMCPMC8569801
OpenAlexW3210650020

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.