ArticleNational science review2021
Boron doping-induced interconnected assembly approach for mesoporous silicon oxycarbide architecture.
Article in National science review, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Mechanical shutdown of battery separators: Silicon anode failure.Nature communications · 2024Article
- Catalytically Active Carbon for Oxygen Reduction Reaction in Energy Conversion: Recent Advances and Future Perspectives.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Review
- Design of a bipolar organic small-molecule cathode with mesoporous nanospheres structure for long lifespan and high-rate Li-storage performance.Chemical science · 2024Article
- Atomic Cu Sites Engineering Enables Efficient CONano-micro letters · 2023Article
- A liquid metal-fluoropolymer artificial protective film enables robust lithium metal batteries at sub-zero temperatures.Chemical science · 2023Article
- Influence of bridge structure manipulation on the electrochemical performance of π-conjugated molecule-bridged silicon quantum dot nanocomposite anode materials for lithium-ion batteries.Nanoscale advances · 2023Article
- Assembly: A Key Enabler for the Construction of Superior Silicon-Based Anodes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
- How to Build a Microplastics-Free Environment: Strategies for Microplastics Degradation and Plastics Recycling.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
- Organic/Inorganic Hybrid Fibers: Controllable Architectures for Electrochemical Energy Applications.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2021Review
- 3D printed silicon-few layer graphene anode for advanced Li-ion batteries.RSC advances · 2021Article
- Multiscale architectures boosting thermoelectric performance of copper sulfide compound.Rare metals · 2021Article
- Cobalt-Based Metal-Organic Frameworks and Their Derivatives for Hydrogen Evolution Reaction.Frontiers in chemistry · 2020Review
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Despite desirable progress in various assembly tactics, the main drawback associated with current assemblies is the weak interparticle connections limited by their assembling protocols. Herein, we report a novel boron doping-induced interconnection-assembly approach for fabricating an unprecedented assembly of mesoporous silicon oxycarbide nanospheres, which are derived from periodic mesoporous organosilicas. The as-prepared architecture is composed of interconnected, strongly coupled nanospheres with coarse surfaces. Significantly, through delicate analysis of the as-formed boron doped species, a novel melt-etching and nucleation-growth mechanism is proposed, which offers a new horizon for the developing interconnected assembling technique. Furthermore, such unique strategy shows precise controllability and versatility, endowing the architecture with tunable interconnection size, surface roughness and switchable primary nanoparticles. Impressively, this interconnected assembly along with tunable surface roughness enables intrinsically dual (both structural and interfacial) stable characteristics, achieving extraordinary long-term cycle life when used as a lithium-ion battery anode.
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